CO2 selective 1D double chain dipyridyl-porphyrin based porous coordination polymers
DC Field | Value | Language |
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dc.contributor.author | Kim, Hyun-Chul | - |
dc.contributor.author | Lee, Young Sun | - |
dc.contributor.author | Huh, Seong | - |
dc.contributor.author | Lee, Suk Joong | - |
dc.contributor.author | Kim, Youngmee | - |
dc.date.accessioned | 2021-09-05T16:53:06Z | - |
dc.date.available | 2021-09-05T16:53:06Z | - |
dc.date.created | 2021-06-15 | - |
dc.date.issued | 2014 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/100994 | - |
dc.description.abstract | Thermal reactions of MnCl(DPyP) (DPyP = 5,15-di(4-pyridyl)-10,20-diphenylporphyrin) as a metalloligand with Co-II and Zn-II ions in dimethylformamide led to neutral one-dimensional (1D) double chain dipyridyl-porphyrin-based porous coordination polymers (PCPs), Co-3(DPyP)(3)center dot 4DMF (I) and Zn-3(DPyP)(3)center dot 2DMF center dot 4H(2)O (II). Both PCPs were structurally characterized by X-ray crystallography. Particularly, the central Mn-III ion in MnCl(DPyP) was transmetallated with Co-II or Zn-II ions and the central Co-II or Zn-II ions were further coordinated to pyridyl groups of neighboring M(DPyP) (M = Co or Zn) porphyrin complexes. PCPs I and II are isostructural and each 1D double chain interacts with another 1D double chain by multiple hydrogen bonding to stabilize the resulting framework. Therefore, solvent-free 1D double chain PCPs have permanent porosity, and the void volumes of the solvent-free I and II are calculated to be 22.6% and 23.0%, respectively. Gas sorption analysis indicated that I and II exhibited selective adsorption of CO2 at 196 K. Both PCPs exhibited much smaller sorption abilities for N-2 (77 K), H-2 (77 K), and CH4 (196 K) than CO2 (196 K). Both PCPs exhibited different PXRD patterns when dried at 373 K, which indicated that the frame-work transformation of the isostructural M-3(DPyP)(3) type of PCPs strongly depended on the type of central metal ions. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | METAL-ORGANIC-FRAMEWORK | - |
dc.subject | POWDER DIFFRACTION PATTERNS | - |
dc.subject | CARBON-DIOXIDE | - |
dc.subject | HYDROGEN-STORAGE | - |
dc.subject | GAS-ADSORPTION | - |
dc.subject | SOLAR-CELLS | - |
dc.subject | MOF | - |
dc.subject | CATALYSIS | - |
dc.subject | DELIVERY | - |
dc.subject | RELIABILITY | - |
dc.title | CO2 selective 1D double chain dipyridyl-porphyrin based porous coordination polymers | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Suk Joong | - |
dc.identifier.doi | 10.1039/c3dt53287a | - |
dc.identifier.scopusid | 2-s2.0-84896470565 | - |
dc.identifier.wosid | 000333122800009 | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.43, no.15, pp.5680 - 5686 | - |
dc.relation.isPartOf | DALTON TRANSACTIONS | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 43 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 5680 | - |
dc.citation.endPage | 5686 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | METAL-ORGANIC-FRAMEWORK | - |
dc.subject.keywordPlus | POWDER DIFFRACTION PATTERNS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | HYDROGEN-STORAGE | - |
dc.subject.keywordPlus | GAS-ADSORPTION | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | MOF | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | DELIVERY | - |
dc.subject.keywordPlus | RELIABILITY | - |
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