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Dehydration-triggered magnetic phase conversion in the porous Cu(II) Mn(III) metal-organic framework dagger

Authors
Ryu, Dae WonShin, Jin HoLim, Kwang SooLee, Woo RamPhang, Won JuYoon, Sung WonSuh, Byoung JinKoh, Eui KwanHong, Chang Seop
Issue Date
2014
Publisher
ROYAL SOC CHEMISTRY
Citation
DALTON TRANSACTIONS, v.43, no.19, pp.6994 - 6997
Indexed
SCIE
SCOPUS
Journal Title
DALTON TRANSACTIONS
Volume
43
Number
19
Start Page
6994
End Page
6997
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/101068
DOI
10.1039/c4dt00222a
ISSN
1477-9226
Abstract
Dehydration of the three-dimensional Cu(II)-Mn(III) coordination network undergoes a dramatic magnetic phase transformation from a paramagnetic state to a long-range magnetic ordered phase with glassy behavior. The gas adsorption behavior and reentrant spin glass character are uniquely apparent in the dehydrated sample.
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