Imidazolium Chloride-LiCl Melts as Efficient Solvents for Cellulose
DC Field | Value | Language |
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dc.contributor.author | Agarwal, Shalu | - |
dc.contributor.author | Hossain, Anwar Md | - |
dc.contributor.author | Choi, Young-Seop | - |
dc.contributor.author | Cheong, Minserk | - |
dc.contributor.author | Jang, Ho Gyeom | - |
dc.contributor.author | Lee, Je Seung | - |
dc.date.accessioned | 2021-09-05T17:51:29Z | - |
dc.date.available | 2021-09-05T17:51:29Z | - |
dc.date.created | 2021-06-15 | - |
dc.date.issued | 2013-12-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/101271 | - |
dc.description.abstract | 1-Alkyl-3-methylimidazolium chloride-LiCl melts were prepared from the reaction of 1-alkyl-3-methylimidazolium chloride ([RMIm]Cl; R=allyl or n-butyl) and lithium chloride, and their ability to dissolve cellulose was evaluated. The solubility of cellulose was greatly increased to 320% when [RMIm]Cl was replaced by [RMIm][LiCl2]. Dissolved cellulose in LiCl/[RMIm]Cl melts was successfully regenerated by adding water and LiCl/[RMIm]Cl melts were easily recovered by removing water. As supported by the computational results, the higher solubility of cellulose in [RMIm][LiCl2] can be ascribed to the increased bond distance between anion and C(2)-H of the imidazolium ring compared with that in [RMIm]Cl, thereby resulting in the increased interaction between [LiCl2](-) and the hydroxyl groups of cellulose.. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.subject | IONIC LIQUIDS | - |
dc.subject | DISSOLUTION | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | SUPERHALOGENS | - |
dc.subject | TEMPERATURE | - |
dc.subject | BEHAVIOR | - |
dc.title | Imidazolium Chloride-LiCl Melts as Efficient Solvents for Cellulose | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jang, Ho Gyeom | - |
dc.identifier.doi | 10.5012/bkcs.2013.34.12.3771 | - |
dc.identifier.scopusid | 2-s2.0-84891347919 | - |
dc.identifier.wosid | 000329144600043 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.34, no.12, pp.3771 - 3776 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 34 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 3771 | - |
dc.citation.endPage | 3776 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001826671 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | IONIC LIQUIDS | - |
dc.subject.keywordPlus | DISSOLUTION | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | SUPERHALOGENS | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordAuthor | Cellulose | - |
dc.subject.keywordAuthor | Dissolution | - |
dc.subject.keywordAuthor | Ionic liquid | - |
dc.subject.keywordAuthor | Lithium chloride | - |
dc.subject.keywordAuthor | Dihedral angle | - |
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