Protodeboronation of ortho- and para-Phenol Boronic Acids and Application to ortho and meta Functionalization of Phenols Using Boronic Acids as Blocking and Directing Groups
DC Field | Value | Language |
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dc.contributor.author | Lee, Chun-Young | - |
dc.contributor.author | Ahn, Su-Jin | - |
dc.contributor.author | Cheon, Cheol-Hong | - |
dc.date.accessioned | 2021-09-05T18:00:18Z | - |
dc.date.available | 2021-09-05T18:00:18Z | - |
dc.date.created | 2021-06-15 | - |
dc.date.issued | 2013-12-06 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/101311 | - |
dc.description.abstract | The first metal-free thermal protodeboronation of ortho- and para-phenol boronic acids in DMSO was developed. The protodeboronation was successfully applied to the synthesis of ortho- and meta-functionalized phenols using the boronic acid moiety as a blocking group and a directing group, respectively. Mechanistic studies suggested that this protodeboronation proceeds through the coordination of water to the boron atom followed by sigma-bond metathesis. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | CROSS-COUPLING REACTIONS | - |
dc.subject | C-H BORYLATION | - |
dc.subject | ARYLBORONIC ACIDS | - |
dc.subject | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject | ARENES | - |
dc.subject | LIGAND | - |
dc.title | Protodeboronation of ortho- and para-Phenol Boronic Acids and Application to ortho and meta Functionalization of Phenols Using Boronic Acids as Blocking and Directing Groups | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cheon, Cheol-Hong | - |
dc.identifier.doi | 10.1021/jo402174v | - |
dc.identifier.scopusid | 2-s2.0-84890186453 | - |
dc.identifier.wosid | 000328231600055 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.78, no.23, pp.12154 - 12160 | - |
dc.relation.isPartOf | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 78 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 12154 | - |
dc.citation.endPage | 12160 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | CROSS-COUPLING REACTIONS | - |
dc.subject.keywordPlus | C-H BORYLATION | - |
dc.subject.keywordPlus | ARYLBORONIC ACIDS | - |
dc.subject.keywordPlus | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject.keywordPlus | ARENES | - |
dc.subject.keywordPlus | LIGAND | - |
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