Warm with high color rendering index white light from hybridization of Ca2BO3Cl:Eu2+ yellow phosphor and CdSe/ZnS nanocrystals

Abstract

Yellow emitting Ca2BO3Cl:Eu2+ phosphor was prepared by solid state reaction at 900 degrees C. The particle was monoclinic crystal structure, and showed broad band emission at around 540-590 nm due to the 5d-4f transition. Single Ca2BO3Cl:Eu2+ phosphor converted white LED exhibited the CIE coordinates of (0.3441, 0.2675) with low CRI of 67.4. Hybridization of Ca2BO3Cl:Eu2+ with 535 and 610 nm emitting CdSe/ZnS nanocrystals contributed to increasing white spectrum and generated the warm color temperature (4055 K) with high CRI (83.9) of white light. The acceptable color stability was also observed from (0.3687, 0.3051) at 20 mA to (0.3645, 0.3101) at 80 mA. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.