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Synthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of the E-coli Siderophore Enterobactin

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dc.contributor.authorBaramov, Todor-
dc.contributor.authorKeijzer, Karlijn-
dc.contributor.authorIrran, Elisabeth-
dc.contributor.authorMoesker, Eva-
dc.contributor.authorBaik, Mu-Hyun-
dc.contributor.authorSuessmuth, Roderich-
dc.date.accessioned2021-09-05T22:59:58Z-
dc.date.available2021-09-05T22:59:58Z-
dc.date.created2021-06-14-
dc.date.issued2013-08-05-
dc.identifier.issn0947-6539-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/102477-
dc.description.abstractThe E. coli siderophore enterobactin, one of the strongest Fe-III chelators known to date, is also capable of binding Si-IV under physiological conditions. We report on the synthesis and structural characterization of the tris(catecholate) Si-IV-enterobactin complex and its Ge-IV and Ti-IV analogues. Comparative structural analysis, supported by quantum-chemical calculations, reveals the correlation between the ionic radius and the structural changes in enterobactin upon complexation.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectMICROBIAL IRON TRANSPORT-
dc.subjectCOORDINATION CHEMISTRY-
dc.subjectSTABILITY-
dc.subjectCHIRALITY-
dc.subjectSURFACES-
dc.subjectADHESION-
dc.subjectCATECHOL-
dc.subjectANALOGS-
dc.subjectDESIGN-
dc.subjectION-
dc.titleSynthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of the E-coli Siderophore Enterobactin-
dc.typeArticle-
dc.contributor.affiliatedAuthorBaik, Mu-Hyun-
dc.identifier.doi10.1002/chem.201301825-
dc.identifier.scopusid2-s2.0-84880964466-
dc.identifier.wosid000322238800020-
dc.identifier.bibliographicCitationCHEMISTRY-A EUROPEAN JOURNAL, v.19, no.32, pp.10536 - 10542-
dc.relation.isPartOfCHEMISTRY-A EUROPEAN JOURNAL-
dc.citation.titleCHEMISTRY-A EUROPEAN JOURNAL-
dc.citation.volume19-
dc.citation.number32-
dc.citation.startPage10536-
dc.citation.endPage10542-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusMICROBIAL IRON TRANSPORT-
dc.subject.keywordPlusCOORDINATION CHEMISTRY-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordPlusCHIRALITY-
dc.subject.keywordPlusSURFACES-
dc.subject.keywordPlusADHESION-
dc.subject.keywordPlusCATECHOL-
dc.subject.keywordPlusANALOGS-
dc.subject.keywordPlusDESIGN-
dc.subject.keywordPlusION-
dc.subject.keywordAuthorenterobactin-
dc.subject.keywordAuthorgermanium-
dc.subject.keywordAuthorsiderophores-
dc.subject.keywordAuthorsilicon-
dc.subject.keywordAuthortitanium-
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