Supramolecular Cl center dot center dot center dot H and O center dot center dot center dot H Interactions in Self-Assembled 1,5-Dichloroanthraquinone Layers on Au(111)
- Authors
- Noh, Seung-Kyun; Jeon, Jeong Heum; Jang, Won Jun; Kim, Howon; Lee, Soon-Hyeong; Lee, Min Wook; Lee, Jhinhwan; Han, Seungwu; Kahng, Se-Jong
- Issue Date
- 15-4월-2013
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- halogen bonds; hydrogen bonds; molecular nanostructures; scanning tunneling microscopy; self-assembly
- Citation
- CHEMPHYSCHEM, v.14, no.6, pp.1177 - 1181
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMPHYSCHEM
- Volume
- 14
- Number
- 6
- Start Page
- 1177
- End Page
- 1181
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/103504
- DOI
- 10.1002/cphc.201201061
- ISSN
- 1439-4235
- Abstract
- The role of halogen bonds in self-assembled networks for systems with Br and I ligands has recently been studied with scanning tunneling microscopy (STM), which provides physical insight at the atomic scale. Here, we study the supramolecular interactions of 1,5-dichloroanthraquinone molecules on Au(111), including Cl ligands, by using STM. Two different molecular structures of chevron and square networks are observed, and their molecular models are proposed. Both molecular structures are stabilized by intermolecular ClH and OH hydrogen bonds with marginal contributions from Cl-related halogen bonds, as revealed by density functional theory calculations. Our study shows that, in contrast to Br- and I-related halogen bonds, Cl-related halogen bonds weakly contribute to the molecular structure due to a modest positive potential (sigma hole) of the Cl ligands.
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Collections - College of Science > Department of Physics > 1. Journal Articles
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