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In situ generation of hydroperoxide by oxidation of benzhydrols to benzophenones using sodium hydride under oxygen atmosphere: use for the oxidative cleavage of cyclic 1,2-diketones to dicarboxylic acids

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dc.contributor.authorKang, Sunhae-
dc.contributor.authorLee, Soyoung-
dc.contributor.authorJeon, Minju-
dc.contributor.authorKim, Sun Min-
dc.contributor.authorKim, Young Sug-
dc.contributor.authorHan, Hogyu-
dc.contributor.authorYang, Jung Woon-
dc.date.accessioned2021-09-06T04:59:42Z-
dc.date.available2021-09-06T04:59:42Z-
dc.date.created2021-06-14-
dc.date.issued2013-01-30-
dc.identifier.issn0040-4039-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/104164-
dc.description.abstractA facile oxidative cleavage of cyclic 1,2-diketones 1 to dicarboxylic acids 3 with hydroperoxide generated in situ has been developed. In situ generation of hydroperoxide was effected by the oxidation of 4,4'-dichlorobenzhydrol 2f to 4,4'-dichlorobenzophenone 41 using sodium hydride under oxygen atmosphere. (C) 2012 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectMAIN-GROUP ELEMENTS-
dc.subjectCIS-DIHYDROXYLATION-
dc.subjectHYDROGEN-PEROXIDE-
dc.subjectTRANSITION-METALS-
dc.subjectFACILE SYNTHESIS-
dc.subjectMULTIPLE BONDS-
dc.subjectALKENES-
dc.subjectMECHANISM-
dc.subjectALDEHYDES-
dc.subjectDERIVATIVES-
dc.titleIn situ generation of hydroperoxide by oxidation of benzhydrols to benzophenones using sodium hydride under oxygen atmosphere: use for the oxidative cleavage of cyclic 1,2-diketones to dicarboxylic acids-
dc.typeArticle-
dc.contributor.affiliatedAuthorHan, Hogyu-
dc.identifier.doi10.1016/j.tetlet.2012.10.127-
dc.identifier.scopusid2-s2.0-84871264343-
dc.identifier.wosid000314328200003-
dc.identifier.bibliographicCitationTETRAHEDRON LETTERS, v.54, no.5, pp.373 - 376-
dc.relation.isPartOfTETRAHEDRON LETTERS-
dc.citation.titleTETRAHEDRON LETTERS-
dc.citation.volume54-
dc.citation.number5-
dc.citation.startPage373-
dc.citation.endPage376-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusMAIN-GROUP ELEMENTS-
dc.subject.keywordPlusCIS-DIHYDROXYLATION-
dc.subject.keywordPlusHYDROGEN-PEROXIDE-
dc.subject.keywordPlusTRANSITION-METALS-
dc.subject.keywordPlusFACILE SYNTHESIS-
dc.subject.keywordPlusMULTIPLE BONDS-
dc.subject.keywordPlusALKENES-
dc.subject.keywordPlusMECHANISM-
dc.subject.keywordPlusALDEHYDES-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordAuthorOxidative cleavage-
dc.subject.keywordAuthorCyclic 1,2-diketone-
dc.subject.keywordAuthorDicarboxylic acid-
dc.subject.keywordAuthorSodium hydride-
dc.subject.keywordAuthorBenzhydrol-
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