1-Dimensional porous alpha-Fe2O3 nanorods as high performance electrode material for supercapacitors
DC Field | Value | Language |
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dc.contributor.author | Chaudhari, Sudeshna | - |
dc.contributor.author | Bhattacharjya, Dhrubajyoti | - |
dc.contributor.author | Yu, Jong-Sung | - |
dc.date.accessioned | 2021-09-06T11:13:05Z | - |
dc.date.available | 2021-09-06T11:13:05Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2013 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/106417 | - |
dc.description.abstract | Porous alpha-Fe2O3 nanorods are successfully synthesized without any templates by a simple wet chemical synthesis method using ferrous sulphate (FeSO4 center dot 7H(2)O) and sodium acetate (CH3COONa) as starting materials. In this method, initially obtained alpha-FeOOH is calcinated at 300 degrees C for 2 h to form 1-dimensional porous alpha-Fe2O3 nanorods. Thermogravimetric analysis (TGA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM) and a gas sorption analyzer are employed to characterize alpha-Fe2O3 porous nanorods. Based on the characterization results, a formation mechanism for alpha-Fe2O3 nanorods is proposed. Electrochemical performance of porous alpha-Fe2O3 nanorods is studied using cyclic (CV) voltammetry, galvanostatic charge/discharge measurements and electrochemical impedance spectroscopy (EIS) in aqueous H3PO4, (NH4)(2)SO4 and Na2SO4 electrolytes. Interestingly, the porous alpha-Fe2O3 nanorod-based electrodes exhibit excellent electrochemical performance, which can be attributed to the high surface area induced by the 1-dimensional porous nanorod structures. The rod shape porous structure facilitates the faster faradic reaction toward electrolytes and delivers highest specific capacitance (308 F g(-1)) and an excellent long cycle life (upto 1000 cycles) in H3PO4 electrolyte, demonstrating that the porous alpha-Fe2O3 nanorods can serve as an excellent electrode material for supercapacitors. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | IRON-OXIDE FILMS | - |
dc.subject | ELECTROCHEMICAL CAPACITOR | - |
dc.subject | HYDROTHERMAL SYNTHESIS | - |
dc.subject | CARBON | - |
dc.subject | GROWTH | - |
dc.subject | MNO2 | - |
dc.subject | NANOPARTICLES | - |
dc.subject | COMPOSITES | - |
dc.subject | MECHANISM | - |
dc.subject | CELLS | - |
dc.title | 1-Dimensional porous alpha-Fe2O3 nanorods as high performance electrode material for supercapacitors | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yu, Jong-Sung | - |
dc.identifier.doi | 10.1039/c3ra44159h | - |
dc.identifier.scopusid | 2-s2.0-84887837810 | - |
dc.identifier.wosid | 000327261000048 | - |
dc.identifier.bibliographicCitation | RSC ADVANCES, v.3, no.47, pp.25120 - 25128 | - |
dc.relation.isPartOf | RSC ADVANCES | - |
dc.citation.title | RSC ADVANCES | - |
dc.citation.volume | 3 | - |
dc.citation.number | 47 | - |
dc.citation.startPage | 25120 | - |
dc.citation.endPage | 25128 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | IRON-OXIDE FILMS | - |
dc.subject.keywordPlus | ELECTROCHEMICAL CAPACITOR | - |
dc.subject.keywordPlus | HYDROTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | CARBON | - |
dc.subject.keywordPlus | GROWTH | - |
dc.subject.keywordPlus | MNO2 | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | COMPOSITES | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | CELLS | - |
dc.subject.keywordAuthor | a-Fe2O3 nanorods | - |
dc.subject.keywordAuthor | electrode material | - |
dc.subject.keywordAuthor | supercapacitors | - |
dc.subject.keywordAuthor | 1-D nanorods | - |
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