Syntheses, structures, and magnetic properties of cyano- and phenoxide-bridged Fe(III)-Mn(III) tetrameric assemblies formed by blocked fac-Fe tricyanide with aliphatic rings
DC Field | Value | Language |
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dc.contributor.author | Cho, Kyung Jin | - |
dc.contributor.author | Ryu, Dae Won | - |
dc.contributor.author | Lim, Kwang Soo | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.contributor.author | Lee, Jin Wuk | - |
dc.contributor.author | Koh, Eui Kwan | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2021-09-06T11:24:50Z | - |
dc.date.available | 2021-09-06T11:24:50Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2013 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/106488 | - |
dc.description.abstract | Three tetranuclear clusters [(Tp(Me,mt3))Fe(CN)(3)Mn(L)](2) (1, L = 5-Clacphmen; 2, L = 5-Clsalen; 3, L = 5-MeO-salen; Tp(Me,mt3) = hydrotris(3-methyl-4,5-propylene-5-methylpyrazol-1-yl)borate) were prepared by assembling the fac-Fe tricyanide with the corresponding Mn Schiff bases. The assembled molecules are linked by cyanide and phenoxide bridges. Weak pi-pi contacts between molecules are evident in these clusters. Compounds 1-3 exhibit slow relaxation of the magnetization. The phenoxide linkers mediate ferromagnetic coupling between the Mn centers, which is ascribed to the long axial Mn-O* length. The overall magnetic exchange coupling nature of the Fe-C N-Mn route is accounted for by the important structural parameters of bridging pathways such as Mn-N-cyano length, Mn-N-cyano-C-cyano angle, and C-eq-Fe center dot center dot center dot Mn-N-eq (eq = equatorial) torsion angle. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | EXHIBITS SLOW RELAXATION | - |
dc.subject | SCHIFF-BASE COMPLEXES | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | HETEROBIMETALLIC CLUSTERS | - |
dc.subject | HETEROMETALLIC CHAINS | - |
dc.subject | ELECTRON-TRANSFER | - |
dc.subject | LOW-SPIN | - |
dc.subject | BEHAVIOR | - |
dc.subject | FAMILY | - |
dc.subject | MN | - |
dc.title | Syntheses, structures, and magnetic properties of cyano- and phenoxide-bridged Fe(III)-Mn(III) tetrameric assemblies formed by blocked fac-Fe tricyanide with aliphatic rings | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1039/c3dt32563f | - |
dc.identifier.scopusid | 2-s2.0-84877085859 | - |
dc.identifier.wosid | 000316869400027 | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.42, no.16, pp.5796 - 5804 | - |
dc.relation.isPartOf | DALTON TRANSACTIONS | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 42 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 5796 | - |
dc.citation.endPage | 5804 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | EXHIBITS SLOW RELAXATION | - |
dc.subject.keywordPlus | SCHIFF-BASE COMPLEXES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | HETEROBIMETALLIC CLUSTERS | - |
dc.subject.keywordPlus | HETEROMETALLIC CHAINS | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | LOW-SPIN | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | FAMILY | - |
dc.subject.keywordPlus | MN | - |
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