Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by 1,2,3,4-Tetrahydroquinoline
DC Field | Value | Language |
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dc.contributor.author | Park, Sun Hee | - |
dc.contributor.author | Kim, Joongyeon | - |
dc.contributor.author | Chun, Jeong Hwan | - |
dc.contributor.author | Chung, Wonkeun | - |
dc.contributor.author | Lee, Chang Hun | - |
dc.contributor.author | Chun, Byung-Hee | - |
dc.contributor.author | Han, Jeong Sik | - |
dc.contributor.author | Jeong, Byung Hun | - |
dc.contributor.author | Han, Hogyu | - |
dc.contributor.author | Kim, Sung Hyun | - |
dc.date.accessioned | 2021-09-06T13:02:56Z | - |
dc.date.available | 2021-09-06T13:02:56Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2012-11-21 | - |
dc.identifier.issn | 0888-5885 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/106921 | - |
dc.description.abstract | We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 1,2,3,4-tetrahydroquinoline (THQ), which acts as a hydrogen donor (H-donor). It was found that conversion of exo-THDCP was faster at the higher temperature. The increase in the rate of <C-10 product formation with increasing temperature was higher than that of >= C-10. Conversion of exo-THDCP was found to be slowed in the presence of THQ The THQ-induced decrease in the conversion of exo-THDCP was smaller at the higher temperature. In addition, the THQ-induced decrease in the rate of <C-10 product formation was smaller than that of >= C-10. We proposed the mechanism for the thermal decomposition of exo-THDCP, which explains the THQ:induced thermal stability improvement of exo-THDCP and suggests a mechanistic basis for developing effective additives capable of lowering C-n formation at high temperatures. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | SIMILAR HYDROCARBON MIXTURES | - |
dc.subject | HIGH-TEMPERATURE STABILIZERS | - |
dc.subject | JET FUELS | - |
dc.subject | HYDROGEN DONORS | - |
dc.subject | SOLID DEPOSITS | - |
dc.subject | JP-10 | - |
dc.subject | PYROLYSIS | - |
dc.subject | CRACKING | - |
dc.subject | DECOMPOSITION | - |
dc.subject | ADDITIVES | - |
dc.title | Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by 1,2,3,4-Tetrahydroquinoline | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Park, Sun Hee | - |
dc.contributor.affiliatedAuthor | Han, Hogyu | - |
dc.contributor.affiliatedAuthor | Kim, Sung Hyun | - |
dc.identifier.doi | 10.1021/ie301199t | - |
dc.identifier.scopusid | 2-s2.0-84869445969 | - |
dc.identifier.wosid | 000311325200003 | - |
dc.identifier.bibliographicCitation | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.51, no.46, pp.14949 - 14957 | - |
dc.relation.isPartOf | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | - |
dc.citation.title | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | - |
dc.citation.volume | 51 | - |
dc.citation.number | 46 | - |
dc.citation.startPage | 14949 | - |
dc.citation.endPage | 14957 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | SIMILAR HYDROCARBON MIXTURES | - |
dc.subject.keywordPlus | HIGH-TEMPERATURE STABILIZERS | - |
dc.subject.keywordPlus | JET FUELS | - |
dc.subject.keywordPlus | HYDROGEN DONORS | - |
dc.subject.keywordPlus | SOLID DEPOSITS | - |
dc.subject.keywordPlus | JP-10 | - |
dc.subject.keywordPlus | PYROLYSIS | - |
dc.subject.keywordPlus | CRACKING | - |
dc.subject.keywordPlus | DECOMPOSITION | - |
dc.subject.keywordPlus | ADDITIVES | - |
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