Dual Temperature and Thiol-Responsive POEOMA-Multisegmented Polydisulfides: Synthesis and Thermoresponsive Properties
DC Field | Value | Language |
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dc.contributor.author | Zhang, Qian | - |
dc.contributor.author | Noh, Seung Man | - |
dc.contributor.author | Nam, Joon Hyun | - |
dc.contributor.author | Jung, Hyun Wook | - |
dc.contributor.author | Park, Jong Myung | - |
dc.contributor.author | Oh, Jung Kwon | - |
dc.date.accessioned | 2021-09-06T15:20:20Z | - |
dc.date.available | 2021-09-06T15:20:20Z | - |
dc.date.created | 2021-06-15 | - |
dc.date.issued | 2012-09-26 | - |
dc.identifier.issn | 1022-1336 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/107434 | - |
dc.description.abstract | New thermoresponsive polydisulfides of POEOMA multiblocks linked with disulfide bonds having redox-responsive properties are reported. These POEOMA-multisegmented polydisulfides were synthesized by a new method employing a combined RAFT/aminolysis and reversible thiol-disulfide redox reaction that centers on the synthesis of new disulfide-labeled difunctional RAFT agent. RAFT polymerization proceeded in living fashion, yielding well-defined POEOMA copolymers with middle disulfides and terminal RAFT species. They were then used as precursors for thiol-disulfide polyexchange induced by aminolysis and reductive reaction followed by oxidation: these polydisulfides with different molecular weights and end groups ex hibited tunable thermoresponsive properties and thiol-responsive degradation. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | FRAGMENTATION CHAIN TRANSFER | - |
dc.subject | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject | RAFT POLYMERIZATION | - |
dc.subject | DRUG-DELIVERY | - |
dc.subject | MACROMOLECULAR DESIGN | - |
dc.subject | MULTIBLOCK COPOLYMERS | - |
dc.subject | REVERSIBLE DISULFIDE | - |
dc.subject | POLYMERS | - |
dc.subject | POLYSTYRENE | - |
dc.subject | POLY(N-ISOPROPYLACRYLAMIDE) | - |
dc.title | Dual Temperature and Thiol-Responsive POEOMA-Multisegmented Polydisulfides: Synthesis and Thermoresponsive Properties | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jung, Hyun Wook | - |
dc.identifier.doi | 10.1002/marc.201200289 | - |
dc.identifier.scopusid | 2-s2.0-84866412546 | - |
dc.identifier.wosid | 000308716200006 | - |
dc.identifier.bibliographicCitation | MACROMOLECULAR RAPID COMMUNICATIONS, v.33, no.18, pp.1528 - 1534 | - |
dc.relation.isPartOf | MACROMOLECULAR RAPID COMMUNICATIONS | - |
dc.citation.title | MACROMOLECULAR RAPID COMMUNICATIONS | - |
dc.citation.volume | 33 | - |
dc.citation.number | 18 | - |
dc.citation.startPage | 1528 | - |
dc.citation.endPage | 1534 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | FRAGMENTATION CHAIN TRANSFER | - |
dc.subject.keywordPlus | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | RAFT POLYMERIZATION | - |
dc.subject.keywordPlus | DRUG-DELIVERY | - |
dc.subject.keywordPlus | MACROMOLECULAR DESIGN | - |
dc.subject.keywordPlus | MULTIBLOCK COPOLYMERS | - |
dc.subject.keywordPlus | REVERSIBLE DISULFIDE | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | POLYSTYRENE | - |
dc.subject.keywordPlus | POLY(N-ISOPROPYLACRYLAMIDE) | - |
dc.subject.keywordAuthor | aminolysis | - |
dc.subject.keywordAuthor | disulfide-thiol exchange | - |
dc.subject.keywordAuthor | LCST | - |
dc.subject.keywordAuthor | polydisulfides | - |
dc.subject.keywordAuthor | RAFT | - |
dc.subject.keywordAuthor | stimuli-sensitive polymers | - |
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