End-to-End Azide-Bridged Manganese(III) Chain Compounds: Field-Induced Magnetic Phase Transitions and Variation of T-C to 38 K Depending on the Side Groups of the Schiff Bases
- Authors
- Yoon, Jung Hee; Lee, Woo Ram; Ryu, Dae Won; Lee, Jin Wuk; Yoon, Sung Won; Suh, Byoung Jin; Kim, Hyoung Chan; Hong, Chang Seop
- Issue Date
- 7-11월-2011
- Publisher
- AMER CHEMICAL SOC
- Citation
- INORGANIC CHEMISTRY, v.50, no.21, pp.10777 - 10785
- Indexed
- SCIE
SCOPUS
- Journal Title
- INORGANIC CHEMISTRY
- Volume
- 50
- Number
- 21
- Start Page
- 10777
- End Page
- 10785
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/111162
- DOI
- 10.1021/ic2013232
- ISSN
- 0020-1669
- Abstract
- Three one-dimensional coordination polymers [Mn(L)(N-3)](n) [L = L1 (1), L2 (2), L3 (3); L1H(2) = N,N'-bis(5-chlorosalicylideneiminato)-1, 3-diaminopentane, L2H(2) = N,N'-bis (5-bromosalicylideneiminato)-1, 3-diaminopentane, L3H(2) = N,N'-bis(5-bromosalicylideneiminato)-1, 3-diamino-2-dimethylpropane] bridged by end-to-end azides were prepared. The crystal systems differ according to the Schiff bases used. Each Mn atom adopts a typical Jahn-Teller distortion. The helicity of the chains occurs in a racemic manner only for 2. No noncovalent forces are relevant in 2, while pi-pi contacts are visible in 1 and 3. Magnetic measurements show the presence of apparent spin canting. Complexes 1 and 3 exhibit a field-induced metamagnetic transition from an antiferromagnetic state to a weak ferromagnetic phase, whereas 2 embraces a field-induced two-step magnetic phase transition. The critical temperature is observed at 38 K for 2, which is relatively higher than those for 1 (11 K) and 3 (10 K). The pronounced long-range order may contribute from intrachain exchange couplings and through-space dipolar interactions between adjacent chains.
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