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Core-shell nanoparticle of silver coated with light-emitting rubrene: Surface plasmon enhanced photoluminescence

Authors
Han, Yoon DeokLee, Jin WooPark, Dong HyukYang, Seung HoKim, Bo KyungKim, JeongyongJoo, Jinsoo
Issue Date
10월-2011
Publisher
ELSEVIER SCIENCE SA
Keywords
Nanoparticle; Core-shell; Rubrene; Silver; Surface plasmon; Photoluminescence
Citation
SYNTHETIC METALS, v.161, no.19-20, pp.2103 - 2106
Indexed
SCIE
SCOPUS
Journal Title
SYNTHETIC METALS
Volume
161
Number
19-20
Start Page
2103
End Page
2106
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/111459
DOI
10.1016/j.synthmet.2011.08.001
ISSN
0379-6779
Abstract
Silver (Ag) nanoparticles (NPs) with a diameter of 50-100 nm were fabricated by using a reduction process of silver nitrate with sodium citrate. Using the Ag NPs, hybrid core (Ag)-shell (organic light-emitting rubrene) NPs were prepared through a hydrothermal process. The formation of hybrid core-shell NP of Ag-rubrene was confirmed through transmission electron microscope images. From ultraviolet and visible absorption spectra, the Ag and rubrene characteristic peaks were simultaneously observed for the core-shell NPs. Using a high-resolution laser confocal microscope (LCM), the photoluminescence (PL) intensity of the Ag-rubrene core-shell single NP was about 300 times higher than that of the rubrene single NP. This remarkable enhancement of PL efficiency in the core-shell single NP is due to the energy transfer effect in the surface plasmon resonance coupling between Ag and rubrene materials. (C) 2011 Elsevier B.V. All rights reserved.
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