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Ionic liquids as benign catalysts for the carbonylation of amines to formamides

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dc.contributor.authorChoi, Young-Seop-
dc.contributor.authorShim, Yu Na-
dc.contributor.authorLee, Jeesun-
dc.contributor.authorYoon, Jung Hee-
dc.contributor.authorHong, Chang Seop-
dc.contributor.authorCheong, Minserk-
dc.contributor.authorKim, Hoon Sik-
dc.contributor.authorJang, Ho Gyeom-
dc.contributor.authorLee, Je Seung-
dc.date.accessioned2021-09-07T08:16:02Z-
dc.date.available2021-09-07T08:16:02Z-
dc.date.created2021-06-19-
dc.date.issued2011-09-19-
dc.identifier.issn0926-860X-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/111573-
dc.description.abstract1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO3]), prepared from the reaction of [BMIm]Cl with K2CO3 in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO3] could be ascribed to the bi-functional actions of [HCO3](-) as a hydrogen atom acceptor and a donor. (C) 2011 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherELSEVIER SCIENCE BV-
dc.subjectOXIDATIVE CARBONYLATION-
dc.subjectIMIDAZOLIUM-
dc.subjectCARBONATE-
dc.subjectCOMPOUND-
dc.subjectANILINE-
dc.subjectACIDS-
dc.subjectMODEL-
dc.titleIonic liquids as benign catalysts for the carbonylation of amines to formamides-
dc.typeArticle-
dc.contributor.affiliatedAuthorHong, Chang Seop-
dc.contributor.affiliatedAuthorJang, Ho Gyeom-
dc.identifier.doi10.1016/j.apcata.2011.07.016-
dc.identifier.scopusid2-s2.0-80052032306-
dc.identifier.wosid000295243500012-
dc.identifier.bibliographicCitationAPPLIED CATALYSIS A-GENERAL, v.404, no.1-2, pp.87 - 92-
dc.relation.isPartOfAPPLIED CATALYSIS A-GENERAL-
dc.citation.titleAPPLIED CATALYSIS A-GENERAL-
dc.citation.volume404-
dc.citation.number1-2-
dc.citation.startPage87-
dc.citation.endPage92-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaEnvironmental Sciences & Ecology-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryEnvironmental Sciences-
dc.subject.keywordPlusOXIDATIVE CARBONYLATION-
dc.subject.keywordPlusIMIDAZOLIUM-
dc.subject.keywordPlusCARBONATE-
dc.subject.keywordPlusCOMPOUND-
dc.subject.keywordPlusANILINE-
dc.subject.keywordPlusACIDS-
dc.subject.keywordPlusMODEL-
dc.subject.keywordAuthorFormamides-
dc.subject.keywordAuthorCarbonylation-
dc.subject.keywordAuthorAmines-
dc.subject.keywordAuthorHydrogen carbonate-
dc.subject.keywordAuthorIonic liquids-
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