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Ferrocene-Appended Aryl Triazole for Electrochemical Recognition of Phosphate Ions

Authors
Cao, Qian-YongPradhan, TuhinKim, SungtaeKim, Jong Seung
Issue Date
19-8월-2011
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.13, no.16, pp.4386 - 4389
Indexed
SCIE
SCOPUS
Journal Title
ORGANIC LETTERS
Volume
13
Number
16
Start Page
4386
End Page
4389
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/111778
DOI
10.1021/ol201722d
ISSN
1523-7060
Abstract
A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C-H center dot center dot center dot O) with a tetrahedral anion, which Is supported by density functional theory based theoretical calculation and H-1 NMR titration results.
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