Click" Synthesis of Thermally Stable Au Nanoparticles with Highly Grafted Polymer Shell and Control of Their Behavior in Polymer Matrix
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lim, Jongmin | - |
dc.contributor.author | Yang, Hyunseung | - |
dc.contributor.author | Paek, Kwanyeol | - |
dc.contributor.author | Cho, Chul-Hee | - |
dc.contributor.author | Kim, Seyong | - |
dc.contributor.author | Bang, Joona | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.date.accessioned | 2021-09-07T09:21:18Z | - |
dc.date.available | 2021-09-07T09:21:18Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2011-08-15 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/111788 | - |
dc.description.abstract | Thermally stable core-shell gold nanoparticles (Au NPs) with highly grafted polymer shells were synthesized by combining reversible addition-fragmentation transfer (RAFT) polymerization and click chemistry of copper-catalyzed azide-alkyne cycloaddition (CuAAC). First, alkyne-terminated poly(4-benzylchloride-b-styrene) (alkyne-PSCl-b-PS) was prepared from the alkyne-terminated RAFT agent. Then, an alkyne-PSCl-b-PS chain was coupled to azide-functionalized Au NPs via the CuAAC reaction. Careful characterization using FTIR, UV-Vis, and TGA showed that PSCl-b-PS chains were successfully grafted onto the Au NP surface with high grafting density. Finally, azide groups were introduced to PSCl-b-PS chains on the Au NP surface to produce thermally stable Au NPs with crosslinkable polymer shell (Au-PSN3-b-PS 1). As the control sample, PS-b-PSN3-coated Au NPs (Au-PSN3-b-PS 2) were made by the conventional "grafting to" approach. The grafting density of polymer chains on Au-PSN3-b-PS 1 was found to be much higher than that on Au-PSN3-b-PS 2. To demonstrate the importance of having the highly packed polymer shell on the nanoparticles, Au-PSN3-b-PS 1 particles were added into the PS and PS-b-poly(2-vinylpyridine) matrix, respectively. Consequently, it was found that Au-PSN3-b-PS 1 nanoparticles were well dispersed in the PS matrix and PS-b-P2VP matrix without any aggregation even after annealing at 220 degrees C for 2 days. Our simple and powerful approach could be easily extended to design other core-shell inorganic nanoparticles. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 3464-3474, 2011 | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.subject | GOLD NANOPARTICLES | - |
dc.subject | BLOCK-COPOLYMERS | - |
dc.subject | ELECTRICAL-PROPERTIES | - |
dc.subject | COATED NANOPARTICLES | - |
dc.subject | SURFACE MODIFICATION | - |
dc.subject | OPTICAL-PROPERTIES | - |
dc.subject | DIBLOCK-COPOLYMER | - |
dc.subject | MOLECULAR-WEIGHT | - |
dc.subject | CHEMISTRY | - |
dc.subject | NANOCOMPOSITES | - |
dc.title | Click" Synthesis of Thermally Stable Au Nanoparticles with Highly Grafted Polymer Shell and Control of Their Behavior in Polymer Matrix | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Seyong | - |
dc.contributor.affiliatedAuthor | Bang, Joona | - |
dc.identifier.doi | 10.1002/pola.24782 | - |
dc.identifier.scopusid | 2-s2.0-79960193581 | - |
dc.identifier.wosid | 000293845800002 | - |
dc.identifier.bibliographicCitation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.49, no.16, pp.3464 - 3474 | - |
dc.relation.isPartOf | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.title | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.volume | 49 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 3464 | - |
dc.citation.endPage | 3474 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | GOLD NANOPARTICLES | - |
dc.subject.keywordPlus | BLOCK-COPOLYMERS | - |
dc.subject.keywordPlus | ELECTRICAL-PROPERTIES | - |
dc.subject.keywordPlus | COATED NANOPARTICLES | - |
dc.subject.keywordPlus | SURFACE MODIFICATION | - |
dc.subject.keywordPlus | OPTICAL-PROPERTIES | - |
dc.subject.keywordPlus | DIBLOCK-COPOLYMER | - |
dc.subject.keywordPlus | MOLECULAR-WEIGHT | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | NANOCOMPOSITES | - |
dc.subject.keywordAuthor | block copolymers | - |
dc.subject.keywordAuthor | click chemistry | - |
dc.subject.keywordAuthor | grafting density | - |
dc.subject.keywordAuthor | nanocomposites | - |
dc.subject.keywordAuthor | nanoparticles | - |
dc.subject.keywordAuthor | polymer coated Au nanoparticles | - |
dc.subject.keywordAuthor | reversible addition fragmentation chain transfer (RAFT) | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.