Multiple intramolecular hydrogen bonds in 2,4-di-tert-butyl-6-[N-(2,6-diisopropylphenyl)-P,P-diphenylphosphorimidoyl]phenol
- Authors
- Lee, Jong-Dae; Suh, Il-Hwan; Kang, Sang Ook
- Issue Date
- 5월-2011
- Publisher
- WILEY-BLACKWELL
- Citation
- ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, v.67, pp.O151 - O153
- Indexed
- SCIE
SCOPUS
- Journal Title
- ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
- Volume
- 67
- Start Page
- O151
- End Page
- O153
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/112588
- DOI
- 10.1107/S0108270111009267
- ISSN
- 0108-2701
- Abstract
- The title compound, C38H48NOP, isolated from the reaction of (2-diphenylphosphanyl-4,6-di-tert-butyl)phenol with 2,6-diisopropylphenyl azide at 273 K, can act as an N,O-bidentate ligand. Crystal structure analysis shows a deviation from ideal tetrahedral symmetry around the P atom. The molecule exists as a monomer in the solid state, whose conformation is stabilized via multiple intramolecular hydrogen bonds. Geometric parameters from both experimental and theoretical calculations are compared.
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Collections - Graduate School > Department of Advanced Materials Chemistry > 1. Journal Articles
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