One-Dimensional End-To-End Azide-Bridged Mn-III Complexes Incorporating Alkali Metal Ions: Slow Magnetic Relaxations and Metamagnetism
DC Field | Value | Language |
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dc.contributor.author | Yoon, Jung Hee | - |
dc.contributor.author | Lee, Jin Wuk | - |
dc.contributor.author | Ryu, Dae Won | - |
dc.contributor.author | Yoon, Sung Won | - |
dc.contributor.author | Suh, Byoung Jin | - |
dc.contributor.author | Kim, Hyoung Chan | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2021-09-07T14:39:30Z | - |
dc.date.available | 2021-09-07T14:39:30Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2011-03 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/112972 | - |
dc.description.abstract | Three azide-bridged Mn-III chains [Mn(3-MeOsalpn)(N-3)]center dot 0.5AClO(4) (A = Na (1), K (2), Rb (3); 3-MeOsalpn = N,N'-propylenebis(3-methoxysalicylideneiminato) dianion) incorporating alkali metal ions and perchlorate anions were systematically synthesized. The overall structure can be described as a one-dimensional chain bridged by end-to-end azide ligands, although spatial arrangements of Jahn-Teller axes of Mn in 1 and 2 are different from that in 3. Relying on the alkali metal ions, magnetic properties are varied from a two-step phase transition (1) to metamagnetic transitions (2 and 3). In this system, spin canting definitely plays a central role in giving rise to the apparent slow magnetic relaxations in 1 and 2 because application of a high external magnetic field tends to destroy single-chain magnet (SCM) properties. Despite the existence of a long-range antiferromagnetic order at T-N, slow magnetic relaxation is notably observed in 2, which likely emanates from the operative spin canting below T-N. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | SINGLE-CHAIN MAGNETS | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | CO(II) CHAIN | - |
dc.subject | CO | - |
dc.subject | BEHAVIOR | - |
dc.subject | FE | - |
dc.subject | 1D | - |
dc.subject | NI | - |
dc.subject | TRANSITION | - |
dc.subject | POLYMERS | - |
dc.title | One-Dimensional End-To-End Azide-Bridged Mn-III Complexes Incorporating Alkali Metal Ions: Slow Magnetic Relaxations and Metamagnetism | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1002/chem.201002269 | - |
dc.identifier.scopusid | 2-s2.0-79951986233 | - |
dc.identifier.wosid | 000288098200030 | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.17, no.10, pp.3028 - 3034 | - |
dc.relation.isPartOf | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 17 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 3028 | - |
dc.citation.endPage | 3034 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | SINGLE-CHAIN MAGNETS | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | CO(II) CHAIN | - |
dc.subject.keywordPlus | CO | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | FE | - |
dc.subject.keywordPlus | 1D | - |
dc.subject.keywordPlus | NI | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordAuthor | azides | - |
dc.subject.keywordAuthor | crystal engineering | - |
dc.subject.keywordAuthor | magnetic properties | - |
dc.subject.keywordAuthor | manganese | - |
dc.subject.keywordAuthor | single-chain magnets | - |
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