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KCN sensor: unique chromogenic and 'turn-on' fluorescent chemodosimeter: rapid response and high selectivity

Authors
Kim, Hyun JungKo, Kyoung ChulLee, Jae HongLee, Jin YongKim, Jong Seung
Issue Date
2011
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.47, no.10, pp.2886 - 2888
Indexed
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
47
Number
10
Start Page
2886
End Page
2888
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/114865
DOI
10.1039/c0cc05018k
ISSN
1359-7345
Abstract
An indole conjugated coumarin 1 for KCN chemodosimeter has been prepared and displayed considerable dual changes in both absorption (blue-shift) and emission (turn-on) bands exclusively for KCN. DFT/TDDFT calculations support that the fluorescence enhancement of 1-KCN is mainly due to blocking of the ICT process.
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