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Charge-compensated Zn metallocenes with sigma-/pi-chelating carboranyl ligands for the formation of constrained geometry Ru(II) and Ni(II) complexes

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dc.contributor.authorLee, Jong-Dae-
dc.contributor.authorHan, Won-Sik-
dc.contributor.authorKim, Tae-Jin-
dc.contributor.authorKim, Sang Hern-
dc.contributor.authorKang, Sang Ook-
dc.date.accessioned2021-09-07T21:31:36Z-
dc.date.available2021-09-07T21:31:36Z-
dc.date.created2021-06-14-
dc.date.issued2011-
dc.identifier.issn1359-7345-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/114954-
dc.description.abstractCharge-compensated zinc metallocenes of types [(eta(3)-C2B9H10)(2)Zn]-[(eta(1)-NMe2)ZnEt](2) (5) and [{eta(3)-(Me)C2B9H9}(2)Zn][(eta(1)-NMe2)-ZnEt](2) (6) were produced by reacting sigma-/pi-chelating aminoalkyl dicarbollides, 7-Me2N(H)CH2-7,8-C2B9H11 (1) and 7-Me2N(H)CH2-8-Me-7,8-C2B9H10 (2), with diethylzinc. Zincocene 5 proved to be an excellent synthon for the formation of dicarbollide-based sigma-/pi-type constrained Ru and Ni complexes.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectCRYSTAL-STRUCTURE-
dc.subjectSANDWICH COMPLEX-
dc.subjectCHEMISTRY-
dc.subjectFERROCENE-
dc.subjectANALOGS-
dc.subjectION-
dc.titleCharge-compensated Zn metallocenes with sigma-/pi-chelating carboranyl ligands for the formation of constrained geometry Ru(II) and Ni(II) complexes-
dc.typeArticle-
dc.contributor.affiliatedAuthorKang, Sang Ook-
dc.identifier.doi10.1039/c0cc03787g-
dc.identifier.scopusid2-s2.0-78650484842-
dc.identifier.wosid000285515200053-
dc.identifier.bibliographicCitationCHEMICAL COMMUNICATIONS, v.47, no.3, pp.1018 - 1020-
dc.relation.isPartOfCHEMICAL COMMUNICATIONS-
dc.citation.titleCHEMICAL COMMUNICATIONS-
dc.citation.volume47-
dc.citation.number3-
dc.citation.startPage1018-
dc.citation.endPage1020-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusSANDWICH COMPLEX-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusFERROCENE-
dc.subject.keywordPlusANALOGS-
dc.subject.keywordPlusION-
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