Effect of pH on electrocatalytic property of supported PtRu catalysts in proton exchange membrane fuel cell
DC Field | Value | Language |
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dc.contributor.author | Kim, Min-Sik | - |
dc.contributor.author | Lim, Sinmuk | - |
dc.contributor.author | Chaudhari, Nitin K. | - |
dc.contributor.author | Fang, Baizeng | - |
dc.contributor.author | Bae, Tea-Sung | - |
dc.contributor.author | Yu, Jong-Sung | - |
dc.date.accessioned | 2021-09-07T22:08:25Z | - |
dc.date.available | 2021-09-07T22:08:25Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2010-12-22 | - |
dc.identifier.issn | 0920-5861 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/115102 | - |
dc.description.abstract | In this study, urea-assisted homogeneous deposition (HD) strategy is employed to synthesize Vulcan XC-72 (VC)-supported Pt-Ru (40 wt%) catalysts under various initial pH conditions. In situ generation of hydroxide ions through hydrolysis of urea at elevated temperature results in HD of Pt-Ru species on the VC support. In addition, it has been found that the initial pH value in the starting solution has significant influence on the Pt-Ru metal particle size and the catalytic activity of the supported Pt-Ru catalyst. Under most pH values investigated (i.e., higher than 5-6), the VC-supported Pt-Ru catalysts prepared by the HD approach have shown smaller metal particle size with better particle dispersion and demonstrated greatly improved anode catalyst performance over the one prepared by impregnation-NaBH4 reduction at pH 7-8 in proton exchange membrane fuel cell. The results presented in this work highlight that highly efficient Pt-based catalysts can be prepared by the HD strategy through the control of the initial pH value in the starting solution. (C) 2010 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | T-BUTYL HYDROPEROXIDE | - |
dc.subject | CATHODE CATALYST | - |
dc.subject | NANOPARTICLE SIZE | - |
dc.subject | CARBON | - |
dc.subject | PLATINUM | - |
dc.subject | EPOXIDATION | - |
dc.subject | REDUCTION | - |
dc.subject | STYRENE | - |
dc.subject | IRRADIATION | - |
dc.subject | OXYGEN | - |
dc.title | Effect of pH on electrocatalytic property of supported PtRu catalysts in proton exchange membrane fuel cell | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yu, Jong-Sung | - |
dc.identifier.doi | 10.1016/j.cattod.2010.04.037 | - |
dc.identifier.wosid | 000284583300027 | - |
dc.identifier.bibliographicCitation | CATALYSIS TODAY, v.158, no.3-4, pp.354 - 360 | - |
dc.relation.isPartOf | CATALYSIS TODAY | - |
dc.citation.title | CATALYSIS TODAY | - |
dc.citation.volume | 158 | - |
dc.citation.number | 3-4 | - |
dc.citation.startPage | 354 | - |
dc.citation.endPage | 360 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | T-BUTYL HYDROPEROXIDE | - |
dc.subject.keywordPlus | CATHODE CATALYST | - |
dc.subject.keywordPlus | NANOPARTICLE SIZE | - |
dc.subject.keywordPlus | CARBON | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | STYRENE | - |
dc.subject.keywordPlus | IRRADIATION | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordAuthor | Homogeneous deposition | - |
dc.subject.keywordAuthor | Urea | - |
dc.subject.keywordAuthor | Electrocatalyst | - |
dc.subject.keywordAuthor | Anode | - |
dc.subject.keywordAuthor | Proton exchange membrane fuel cell | - |
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