Direct Synthesis of Pyrazolo[5,1-alpha]isoindoles via Intramolecular Palladium-Catalyzed C-H Bond Activation
DC Field | Value | Language |
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dc.contributor.author | Choi, Young Lok | - |
dc.contributor.author | Lee, Hyuk | - |
dc.contributor.author | Kim, Bum Tae | - |
dc.contributor.author | Choi, Kihang | - |
dc.contributor.author | Heo, Jung-Nyoung | - |
dc.date.accessioned | 2021-09-08T01:10:21Z | - |
dc.date.available | 2021-09-08T01:10:21Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2010-08 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/115946 | - |
dc.description.abstract | An efficient. direct synthesis of pyrazolo-[5.1-alpha]isoindoles employing a palladium-catalyzed intramolecular C-H bond activation of 1-(2-halobenzyl)pyrazoles has been developed The use of lithium chloride (LICI) was found to be essential in these reactions, to suppress further C H bond activation at the C-3 position of pyrazolo[5,1-alpha]isoindole, when C-3 is unsubstituted This protocol can be applied to the synthesis of a pyrazolo(5,1-alpha]isoqumnoline possessing a six-membered central ring system and a fully substituted pyrazolo[5,1-alpha]isoindole using seciuential intra- and intermolecular C-H bond activation | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | DIRECT ARYLATION | - |
dc.subject | NITROGEN-HETEROCYCLES | - |
dc.subject | ROOM-TEMPERATURE | - |
dc.subject | BENZOIC-ACIDS | - |
dc.subject | ARYL | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | POTENT | - |
dc.subject | 1,2,3-TRIAZOLES | - |
dc.subject | 2H-INDAZOLES | - |
dc.subject | LIGANDS | - |
dc.title | Direct Synthesis of Pyrazolo[5,1-alpha]isoindoles via Intramolecular Palladium-Catalyzed C-H Bond Activation | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Choi, Kihang | - |
dc.identifier.doi | 10.1002/adsc.201000260 | - |
dc.identifier.scopusid | 2-s2.0-77956378879 | - |
dc.identifier.wosid | 000281654500032 | - |
dc.identifier.bibliographicCitation | ADVANCED SYNTHESIS & CATALYSIS, v.352, no.11-12, pp.2041 - 2049 | - |
dc.relation.isPartOf | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.title | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.volume | 352 | - |
dc.citation.number | 11-12 | - |
dc.citation.startPage | 2041 | - |
dc.citation.endPage | 2049 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | DIRECT ARYLATION | - |
dc.subject.keywordPlus | NITROGEN-HETEROCYCLES | - |
dc.subject.keywordPlus | ROOM-TEMPERATURE | - |
dc.subject.keywordPlus | BENZOIC-ACIDS | - |
dc.subject.keywordPlus | ARYL | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | POTENT | - |
dc.subject.keywordPlus | 1,2,3-TRIAZOLES | - |
dc.subject.keywordPlus | 2H-INDAZOLES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordAuthor | C-H activation | - |
dc.subject.keywordAuthor | direct arylation | - |
dc.subject.keywordAuthor | palladium | - |
dc.subject.keywordAuthor | pyrazoles | - |
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