Cosolvent effect on the phase behavior for the poly(benzyl acrylate) and poly(benzyl methacrylate) in supercritical carbon dioxide and dimethyl ether
DC Field | Value | Language |
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dc.contributor.author | Jang, Yoon-Seok | - |
dc.contributor.author | Kang, Jeong-Won | - |
dc.contributor.author | Byun, Hun-Soo | - |
dc.date.accessioned | 2021-09-08T01:28:57Z | - |
dc.date.available | 2021-09-08T01:28:57Z | - |
dc.date.created | 2021-06-14 | - |
dc.date.issued | 2010-07-25 | - |
dc.identifier.issn | 1226-086X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/116043 | - |
dc.description.abstract | Experimental cloud-point data up to 433.2 K and 193.0 MPa are reported for binary and ternary mixtures of poly(benzyl methacrylate) [poly(BzMA)] + carbon dioxide + benzyl methacrylate (BzMA) and poly(benzyl acrylate) [Poly(BzA)]+ carbon dioxide + benzyl acrylate (BzA) systems. High-pressure cloud-point data are also reported for Poly(BzMA) + carbon dioxide and Poly(BzA) + carbon dioxide in supercritical dimethyl ether (DME). Cloud-point behavior for the Poly(BzMA) + carbon dioxide + BzMA system was measured in changes of the pressure-temperature (p-T) slope, and with BzMA weight fraction of 50.6, 61.0, 67.2 and 95.0 wt.%. The Poly(BzA) + carbon dioxide + 30.4, 40.7 and 49.4 wt.% BzA systems change the (p-T) curve from upper critical solution temperature region (UCST) to lower critical solution temperature (LCST) region as the BzA concentration increases. With 52.3 wt.% BzA to the Poly(BzA) + carbon dioxide solution, the cloud-point curves are taken on the appearance of a typical lower critical solution temperature boundary. Also, the impact by cosolvent (BzMA and BzA) concentrations for the Poly(BzMA) + DME and Poly(BzA) + DME systems is measured at temperature to 453.2 K and pressure range of 24.6-61.3 MPa. (C) 2010 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE INC | - |
dc.subject | TERNARY MIXTURES | - |
dc.subject | SOLVENTS | - |
dc.subject | SYSTEMS | - |
dc.subject | BINARY | - |
dc.subject | POLYMERS | - |
dc.subject | ACETATE | - |
dc.subject | CO2 | - |
dc.title | Cosolvent effect on the phase behavior for the poly(benzyl acrylate) and poly(benzyl methacrylate) in supercritical carbon dioxide and dimethyl ether | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kang, Jeong-Won | - |
dc.identifier.doi | 10.1016/j.jiec.2010.03.013 | - |
dc.identifier.scopusid | 2-s2.0-77954862523 | - |
dc.identifier.wosid | 000278778800019 | - |
dc.identifier.bibliographicCitation | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.16, no.4, pp.598 - 601 | - |
dc.relation.isPartOf | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | - |
dc.citation.title | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | - |
dc.citation.volume | 16 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 598 | - |
dc.citation.endPage | 601 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001465906 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | TERNARY MIXTURES | - |
dc.subject.keywordPlus | SOLVENTS | - |
dc.subject.keywordPlus | SYSTEMS | - |
dc.subject.keywordPlus | BINARY | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | ACETATE | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordAuthor | Phase behavior | - |
dc.subject.keywordAuthor | CO(2) | - |
dc.subject.keywordAuthor | Dimethyl ether | - |
dc.subject.keywordAuthor | Poly(benzyl acrylate) | - |
dc.subject.keywordAuthor | Poly(benzyl methacrylate) | - |
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