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Investigation of curing kinetics of various cycloaliphatic epoxy resins using dynamic thermal analysis

Authors
Yoo, Myong JaeKim, Sang HyunPark, Seong DaeLee, Woo SungSun, Jong-WooChoi, Jae-HongNahm, Sahn
Issue Date
5월-2010
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
Cure kinetics; Cycloaliphatic epoxy resin; Differential scanning calorimetry; Activation energy
Citation
EUROPEAN POLYMER JOURNAL, v.46, no.5, pp.1158 - 1162
Indexed
SCIE
SCOPUS
Journal Title
EUROPEAN POLYMER JOURNAL
Volume
46
Number
5
Start Page
1158
End Page
1162
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/116596
DOI
10.1016/j.eurpolymj.2010.02.001
ISSN
0014-3057
Abstract
Curing reactions of three cycloaliphatic epoxy resins with methyltetrahydrophthalic anhydride (MTHPA) was investigated by differential scanning calorimetry at different heating rates. Activation energy was calculated based on Kissinger method and varied in the range of 67-72 kJ/mol depending on sample. The curing kinetic behavior was well described by Sestak-Berggren (SB) model and the order of the curing reaction is observed to be from 0.02 to 2.11 according to sample. (C) 2010 Elsevier Ltd. All rights reserved.
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