Phosphine-Catalyzed Si-C Coupling of Bissilylmethanes: Preparation of Cyclic (Cl2SiCH2)(2) and Linear Cl2Si(CH2SiCl3)(2) via Silylene and Silene Intermediates
DC Field | Value | Language |
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dc.contributor.author | Hong, Soon Hyun | - |
dc.contributor.author | Hyun, Sang Il | - |
dc.contributor.author | Jung, Il Nam | - |
dc.contributor.author | Han, Won-Sik | - |
dc.contributor.author | Kim, Min-Hye | - |
dc.contributor.author | Yun, Hoseop | - |
dc.contributor.author | Nam, Suk-Woo | - |
dc.contributor.author | Kang, Sang Ook | - |
dc.date.accessioned | 2021-09-08T05:08:19Z | - |
dc.date.available | 2021-09-08T05:08:19Z | - |
dc.date.created | 2021-06-11 | - |
dc.date.issued | 2010-02-08 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/116995 | - |
dc.description.abstract | Cyclic and linear carbosilanes. (Cl2SiCH2)(2) (2) and Cl2Si(CH2SiCl3)(2) (3), were produced from phosphine-catalized Si-C coupling reactions of bissilylmethanes, HCl2SiCH2SiX1X2Cl (X-1, X-2 = Cl (1), X-1 = H, X-2, = Cl (7), and X-1 = Me, X-2 = Cl (8)). The formation of compounds 2 and 3 suggested competing reaction pathways, involving dichlorosilene [CH2=SiCl2] and dichlorosilylene [:SiCl2] intermediates. Each intermediate was either proposed by the product isolation of the trimerized product (3) or confirmed by trapping experiments with 2,3-dimethylbutadiene and methylene chloride. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | CARBOSILANE DENDRIMER | - |
dc.subject | ELEMENTAL SILICON | - |
dc.subject | ALKYL-HALIDES | - |
dc.subject | CHLORIDE | - |
dc.subject | TRICHLOROSILANE | - |
dc.subject | KINETICS | - |
dc.subject | CARBIDE | - |
dc.title | Phosphine-Catalyzed Si-C Coupling of Bissilylmethanes: Preparation of Cyclic (Cl2SiCH2)(2) and Linear Cl2Si(CH2SiCl3)(2) via Silylene and Silene Intermediates | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Nam, Suk-Woo | - |
dc.contributor.affiliatedAuthor | Kang, Sang Ook | - |
dc.identifier.doi | 10.1021/om901071k | - |
dc.identifier.scopusid | 2-s2.0-76149114609 | - |
dc.identifier.wosid | 000274015800025 | - |
dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.29, no.3, pp.687 - 691 | - |
dc.relation.isPartOf | ORGANOMETALLICS | - |
dc.citation.title | ORGANOMETALLICS | - |
dc.citation.volume | 29 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 687 | - |
dc.citation.endPage | 691 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | CARBOSILANE DENDRIMER | - |
dc.subject.keywordPlus | ELEMENTAL SILICON | - |
dc.subject.keywordPlus | ALKYL-HALIDES | - |
dc.subject.keywordPlus | CHLORIDE | - |
dc.subject.keywordPlus | TRICHLOROSILANE | - |
dc.subject.keywordPlus | KINETICS | - |
dc.subject.keywordPlus | CARBIDE | - |
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