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Significance of Hydrophilic Characters of Organic Dyes in Visible-Light Hydrogen Generation Based on TiO2

Authors
Lee, Su-HyunPark, YiseulWee, Kyung-RyangSon, Ho-JinCho, Dae WonPac, ChyongjinChoi, WonyongKang, Sang Ook
Issue Date
5-2월-2010
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.12, no.3, pp.460 - 463
Indexed
SCIE
SCOPUS
Journal Title
ORGANIC LETTERS
Volume
12
Number
3
Start Page
460
End Page
463
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/117000
DOI
10.1021/ol9026182
ISSN
1523-7060
Abstract
A series of dyes were synthesized to examine the roles of the hydrophilic characteristics of R in sensitized hydrogen generation by dyegrafted Pt/TiO2 under visible light irradiation. The hydrogen-generation efficiencies and optimum amounts of the dyes grafted to Pt/TiO2 were affected substantially by the hydrophilic and steric effects of R; moderately hydrophilic DEO1 and DEO2 showed higher sensitization activity at a lower loading than hydrophobic D-H.
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