Chiral organotin complexes stabilized by C,N-chelating oxazolinyl-o-carboranes
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Jong-Dae | - |
dc.contributor.author | Kim, Hyo-Suk | - |
dc.contributor.author | Han, Won-Sik | - |
dc.contributor.author | Kang, Sang Ook | - |
dc.date.accessioned | 2021-09-08T05:13:56Z | - |
dc.date.available | 2021-09-08T05:13:56Z | - |
dc.date.created | 2021-06-11 | - |
dc.date.issued | 2010-02-01 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/117013 | - |
dc.description.abstract | A series of chiral organotin halides containing 2-(4-R)-oxazolinyl-o-carboranes (R = i-propyl 1, t-butyl 2; Cab(Oxa)) was prepared from o-carborane with a chiral oxazoline auxiliary. X-ray structural analysis of the representative chiral organotin halide, [2-(4-i-propyl)-oxazolinyl-o-carboranyl]SnMe(2)Br (4), revealed the formation of a stable penta-coordinated tin center due to a N -> Sn interaction. Similar O -> Sn assisted intramolecular penta-coordinated tin complexes (9 and 10) were prepared from methoxy-o-carborane ligands, MeOCH(Z)-o-carborane (Z = H 7, Ph 8; Cab(OMe)), respectively, and a rigid o-carboranyl backbone provided the basic skeleton for the facile formation of organotin complexes. (C) 2009 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | ASYMMETRIC CATALYSIS | - |
dc.subject | CONTAINING LIGANDS | - |
dc.subject | RADICAL REACTIONS | - |
dc.subject | DERIVATIVES | - |
dc.subject | TIN | - |
dc.subject | COORDINATION | - |
dc.subject | TRIORGANOTIN | - |
dc.subject | HALIDES | - |
dc.subject | C-13 | - |
dc.subject | CL | - |
dc.title | Chiral organotin complexes stabilized by C,N-chelating oxazolinyl-o-carboranes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kang, Sang Ook | - |
dc.identifier.doi | 10.1016/j.jorganchem.2009.10.030 | - |
dc.identifier.wosid | 000273782000022 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.695, no.3, pp.463 - 468 | - |
dc.relation.isPartOf | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
dc.citation.title | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
dc.citation.volume | 695 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 463 | - |
dc.citation.endPage | 468 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | ASYMMETRIC CATALYSIS | - |
dc.subject.keywordPlus | CONTAINING LIGANDS | - |
dc.subject.keywordPlus | RADICAL REACTIONS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | TIN | - |
dc.subject.keywordPlus | COORDINATION | - |
dc.subject.keywordPlus | TRIORGANOTIN | - |
dc.subject.keywordPlus | HALIDES | - |
dc.subject.keywordPlus | C-13 | - |
dc.subject.keywordPlus | CL | - |
dc.subject.keywordAuthor | Organotin complexes | - |
dc.subject.keywordAuthor | Chiral oxazoline | - |
dc.subject.keywordAuthor | o-Carborane backbone | - |
dc.subject.keywordAuthor | Intramolecular coordination | - |
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