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Photoactive Deoxyribonucleic Acid (DNA) Bearing Carbazole Moieties and Its Photoluminescence Behavior With Ir(III) Complex

Authors
Kim, Youn SunLee, U. RaLee, Jung EunCho, Min JuJin, Jung-IlShin, Dong HeeChoi, Suk-HoChoi, Dong Hoon
Issue Date
2010
Publisher
TAYLOR & FRANCIS LTD
Keywords
Cz-DNA; isolation effect; natural DNA; photoluminescence; PVK
Citation
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.519, pp.227 - 233
Indexed
SCIE
SCOPUS
Journal Title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
Volume
519
Start Page
227
End Page
233
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/118708
DOI
10.1080/15421401003598173
ISSN
1542-1406
Abstract
The preparation of organic-soluble DNA bearing carbazole side chain (Cz-DNA) was carried out and the resulting Cz-DNA shows good solubility in alcohol, which allows the fabrication of thin films for studying the photophysical properties of DNA in a solid state. We demonstrated the absorption and photoluminescence behaviors of new soluble Ir(III) complex in two polymer hosts of Cz-DNA and poly(N-vinylcarbazole) (PVK). We compared the absorption and photoluminescence (PL) spectra with the concentration of Ir(III) complex. The Ir(Cz-ppy)(3) in Cz-DNA was observed to have a larger quantum yield and induce enhancement of green emission of Ir(Cz-ppy)(3).
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