Photophysics of a new photosensitizer with high quantum yield of singlet oxygen generation and its application to stereo-selective synthesis of (+)-deoxoartemisinin
DC Field | Value | Language |
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dc.contributor.author | Wang, Kang-Kyun | - |
dc.contributor.author | Choi, Kyoung-Hoon | - |
dc.contributor.author | Shin, Hee-Won | - |
dc.contributor.author | Kim, Bong-Jin | - |
dc.contributor.author | Im, Ji-Eun | - |
dc.contributor.author | Oh, Seung-Lim | - |
dc.contributor.author | Park, Nam-Soo | - |
dc.contributor.author | Jung, Mankil | - |
dc.contributor.author | Oh, Jae-Buem | - |
dc.contributor.author | Lee, Myung-Jun | - |
dc.contributor.author | Kim, Hwan-Kyu | - |
dc.contributor.author | Kim, Yong-Rok | - |
dc.date.accessioned | 2021-09-08T11:34:44Z | - |
dc.date.available | 2021-09-08T11:34:44Z | - |
dc.date.created | 2021-06-11 | - |
dc.date.issued | 2009-11-06 | - |
dc.identifier.issn | 0009-2614 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/118932 | - |
dc.description.abstract | A new photo-catalyst of [5,10,15-triphenyl-20-(4-methoxycarbonylphenyl)-porphyrin] platinum was synthesized and its photophysical study revealed that it had a high quantum yield of singlet oxygen generation. As an application study, a stereo-specific synthesis of (+)-deoxoartemisinin was performed. The induced high triplet quantum yield (0.96 +/- 0.03) of [5,10,15-triphenyl-20-(4-methoxycarbonylphenyl)porphyrin] resulted the high singlet oxygen quantum yield of 0.90 +/- 0.04. The photo-catalytic effect was compared with that of methylene blue (MB) which was generally used as a photo-catalyst for these types of stereo-specific syntheses of organic compounds. The yield of synthesized (+)-deoxoartemisinin was correlated with singlet oxygen quantum yield. (C) 2009 Elsevier B. V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.subject | WATER DISINFECTION | - |
dc.subject | EFFICIENCY FACTORS | - |
dc.subject | PORPHYRIN | - |
dc.subject | PHOTOCHEMISTRY | - |
dc.subject | LUMINESCENCE | - |
dc.subject | RELAXATION | - |
dc.subject | CONVERSION | - |
dc.subject | COMPLEXES | - |
dc.subject | OXIDATION | - |
dc.subject | THERAPY | - |
dc.title | Photophysics of a new photosensitizer with high quantum yield of singlet oxygen generation and its application to stereo-selective synthesis of (+)-deoxoartemisinin | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Hwan-Kyu | - |
dc.identifier.doi | 10.1016/j.cplett.2009.09.081 | - |
dc.identifier.scopusid | 2-s2.0-72049095302 | - |
dc.identifier.wosid | 000271264600015 | - |
dc.identifier.bibliographicCitation | CHEMICAL PHYSICS LETTERS, v.482, no.1-3, pp.81 - 86 | - |
dc.relation.isPartOf | CHEMICAL PHYSICS LETTERS | - |
dc.citation.title | CHEMICAL PHYSICS LETTERS | - |
dc.citation.volume | 482 | - |
dc.citation.number | 1-3 | - |
dc.citation.startPage | 81 | - |
dc.citation.endPage | 86 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Physics, Atomic, Molecular & Chemical | - |
dc.subject.keywordPlus | WATER DISINFECTION | - |
dc.subject.keywordPlus | EFFICIENCY FACTORS | - |
dc.subject.keywordPlus | PORPHYRIN | - |
dc.subject.keywordPlus | PHOTOCHEMISTRY | - |
dc.subject.keywordPlus | LUMINESCENCE | - |
dc.subject.keywordPlus | RELAXATION | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | THERAPY | - |
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