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Synthesis and structure of penta-platinum sigma-bonded derivatives of corannulene
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Choi, Hyunbong | - |
| dc.contributor.author | Kim, Chulwoo | - |
| dc.contributor.author | Park, Ki-Min | - |
| dc.contributor.author | Kim, Jinho | - |
| dc.contributor.author | Kang, Youngjin | - |
| dc.contributor.author | Ko, Jaejung | - |
| dc.date.accessioned | 2021-09-08T12:28:48Z | - |
| dc.date.available | 2021-09-08T12:28:48Z | - |
| dc.date.created | 2021-06-11 | - |
| dc.date.issued | 2009-10-15 | - |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/119111 | - |
| dc.description.abstract | The synthesis of a new class of Pt(II) complexes with corannulene by way of either oxidative addition or reductive coupling is reported and their crystal structures are investigated. The crystal structure for {trans-Pt(PEt3)(2)Cl}(4){cis-Pt(PEt3)(2)Cl}C20H5 (1) consists of two enantiomers in a unit cell and shows cis- and trans-configuration around Pt(II) due to bulky PEt3 ligands. The pentanuclear Pt(II) complex, 1, readily reacts with 1-ethynyl-4-nitrobenzene to afford the penta-alkynyl substituted Pt(II) complex (2). Although there are still bulky PEt3 ligands around the Pt atoms in 2, all five Pt(II) have trans-configurations. The bowl of corannulene in 2 is shallower than that of 1. Therefore, the bowl depth of corannulene plays a key role in the determination of molecular geometry of sigma-bonded pentanuclear complexes bearing corannulene. (C) 2009 Elsevier B. V. All rights reserved. | - |
| dc.language | English | - |
| dc.language.iso | en | - |
| dc.publisher | ELSEVIER SCIENCE SA | - |
| dc.subject | NORMAL-COORDINATE CALCULATIONS | - |
| dc.subject | PHASE MOLECULAR-STRUCTURE | - |
| dc.subject | TO-BOWL INVERSION | - |
| dc.subject | ELECTRON-DIFFRACTION | - |
| dc.subject | GEODESIC POLYARENE | - |
| dc.subject | AB-INITIO | - |
| dc.subject | BUCKYBOWL | - |
| dc.subject | FULLERENES | - |
| dc.subject | COMPLEX | - |
| dc.subject | BARRIER | - |
| dc.title | Synthesis and structure of penta-platinum sigma-bonded derivatives of corannulene | - |
| dc.type | Article | - |
| dc.contributor.affiliatedAuthor | Ko, Jaejung | - |
| dc.identifier.doi | 10.1016/j.jorganchem.2009.07.015 | - |
| dc.identifier.scopusid | 2-s2.0-69949093625 | - |
| dc.identifier.wosid | 000269723700001 | - |
| dc.identifier.bibliographicCitation | JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.694, no.22, pp.3529 - 3532 | - |
| dc.relation.isPartOf | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
| dc.citation.title | JOURNAL OF ORGANOMETALLIC CHEMISTRY | - |
| dc.citation.volume | 694 | - |
| dc.citation.number | 22 | - |
| dc.citation.startPage | 3529 | - |
| dc.citation.endPage | 3532 | - |
| dc.type.rims | ART | - |
| dc.type.docType | Article | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | NORMAL-COORDINATE CALCULATIONS | - |
| dc.subject.keywordPlus | PHASE MOLECULAR-STRUCTURE | - |
| dc.subject.keywordPlus | TO-BOWL INVERSION | - |
| dc.subject.keywordPlus | ELECTRON-DIFFRACTION | - |
| dc.subject.keywordPlus | GEODESIC POLYARENE | - |
| dc.subject.keywordPlus | AB-INITIO | - |
| dc.subject.keywordPlus | BUCKYBOWL | - |
| dc.subject.keywordPlus | FULLERENES | - |
| dc.subject.keywordPlus | COMPLEX | - |
| dc.subject.keywordPlus | BARRIER | - |
| dc.subject.keywordAuthor | Corannulene | - |
| dc.subject.keywordAuthor | Oxidative addition | - |
| dc.subject.keywordAuthor | X-ray structure | - |
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