Synthesis and Reactivity of a Mononuclear Manganese(II) Complex Having Pseudo-Seven Coordination Environment
DC Field | Value | Language |
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dc.contributor.author | Yoon, Jeehee | - |
dc.contributor.author | Seo, Mi Sook | - |
dc.contributor.author | Kim, Youngmee | - |
dc.contributor.author | Kim, Sung-Jin | - |
dc.contributor.author | Yoon, Sungho | - |
dc.contributor.author | Jang, Ho G. | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.accessioned | 2021-09-08T18:50:53Z | - |
dc.date.available | 2021-09-08T18:50:53Z | - |
dc.date.created | 2021-06-10 | - |
dc.date.issued | 2009-03-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/120413 | - |
dc.description.abstract | Utilizing a planar five coordinating N3S2 ligand, 2 6-bis(2-methylthiophenyliminomethyl)pyridine, a pseudo 7-coordinated manganese(II) complex with two labile triflate anions in the axial positions was synthesized. The reaction of the manganese(II) complex with an oxidant, iodosylbenzene, produced a metastable high-valent manganese(IV)-oxo species at 0 degrees C. The high-valent Mn(IV)-oxo intermediate was characterized with a UV-vis spectrophotometer and an electrospray ionization mass spectroscopy. Reactivity studies of the Mn(IV)=O species revealed that the intermediate is capable of oxygenating PPh3 and N-dealkylating N,N-dimethyl-toludine. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | FLASH-PHOTOLYSIS GENERATION | - |
dc.subject | OXYGEN-ATOM TRANSFER | - |
dc.subject | OXOMANGANESE(V) PORPHYRIN | - |
dc.subject | NONHEME IRON(IV)-OXO | - |
dc.subject | LIGANDS | - |
dc.subject | EPOXIDATION | - |
dc.subject | OXIDATIONS | - |
dc.subject | EVOLUTION | - |
dc.subject | OXIDIZE | - |
dc.subject | WATER | - |
dc.title | Synthesis and Reactivity of a Mononuclear Manganese(II) Complex Having Pseudo-Seven Coordination Environment | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jang, Ho G. | - |
dc.identifier.scopusid | 2-s2.0-73249137747 | - |
dc.identifier.wosid | 000265240000029 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.30, no.3, pp.679 - 682 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 30 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 679 | - |
dc.citation.endPage | 682 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001524303 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | FLASH-PHOTOLYSIS GENERATION | - |
dc.subject.keywordPlus | OXYGEN-ATOM TRANSFER | - |
dc.subject.keywordPlus | OXOMANGANESE(V) PORPHYRIN | - |
dc.subject.keywordPlus | NONHEME IRON(IV)-OXO | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordPlus | OXIDATIONS | - |
dc.subject.keywordPlus | EVOLUTION | - |
dc.subject.keywordPlus | OXIDIZE | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordAuthor | Bioinorganic chemistry | - |
dc.subject.keywordAuthor | Seven coordination | - |
dc.subject.keywordAuthor | High-valent manganese-oxo | - |
dc.subject.keywordAuthor | Oxygenation | - |
dc.subject.keywordAuthor | N-Dealkylation | - |
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