Concomitant polymorphism of an antiferromagnetically coupled dicopper(II,II) complex with single strand helical assembly: Synthesis, structure, DSC, magnetic and heterogeneous catalytic studies
DC Field | Value | Language |
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dc.contributor.author | Mijanuddin, Md. | - |
dc.contributor.author | Jana, Atish Dipankar | - |
dc.contributor.author | Drew, Michael G. B. | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.contributor.author | Chattopadhyay, Basab | - |
dc.contributor.author | Mukherjee, Monika | - |
dc.contributor.author | Nandi, Mahasweta | - |
dc.contributor.author | Bhaumik, Asim | - |
dc.contributor.author | Helliwell, Madeline | - |
dc.contributor.author | Mostafa, Golam | - |
dc.contributor.author | Ali, Mahammad | - |
dc.date.accessioned | 2021-09-08T18:54:06Z | - |
dc.date.available | 2021-09-08T18:54:06Z | - |
dc.date.issued | 2009-03-12 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.issn | 1873-3719 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/120429 | - |
dc.description.abstract | Two concomitant polymorphic coordination complexes (dark blue - I and black - II) with the formula (Cu2C44H60N4O4) have been synthesized and characterized crystallographically. Magnetic measurements show the presence of a strong antiferromagnetic interaction and the 2J value corresponds extremely well to the theoretically calculated one, indicating the fact that it follows nicely the magneto-structural relationship. Immobilization of the copper(II) complex I on a 2D-hexagonal mesoporous silica showed good catalytic efficiency in the liquid phase partial oxidation of olefins in the presence of TBHP as an oxidant. (C) 2009 Elsevier Ltd. All rights reserved. | - |
dc.format.extent | 8 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Concomitant polymorphism of an antiferromagnetically coupled dicopper(II,II) complex with single strand helical assembly: Synthesis, structure, DSC, magnetic and heterogeneous catalytic studies | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.1016/j.poly.2008.12.047 | - |
dc.identifier.scopusid | 2-s2.0-60349127695 | - |
dc.identifier.wosid | 000264695400004 | - |
dc.identifier.bibliographicCitation | POLYHEDRON, v.28, no.4, pp 665 - 672 | - |
dc.citation.title | POLYHEDRON | - |
dc.citation.volume | 28 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 665 | - |
dc.citation.endPage | 672 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.subject.keywordPlus | RAY CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | GALACTOSE-OXIDASE | - |
dc.subject.keywordPlus | COPPER(II) COMPLEXES | - |
dc.subject.keywordPlus | AEROBIC OXIDATION | - |
dc.subject.keywordPlus | CU-II | - |
dc.subject.keywordPlus | DINUCLEAR COPPER(II) | - |
dc.subject.keywordPlus | MOLECULAR-CRYSTALS | - |
dc.subject.keywordPlus | MACROCYCLIC LIGAND | - |
dc.subject.keywordPlus | MESOPOROUS SILICA | - |
dc.subject.keywordPlus | PRIMARY ALCOHOLS | - |
dc.subject.keywordAuthor | Cu-II-complexes | - |
dc.subject.keywordAuthor | Concomitant polymorphism | - |
dc.subject.keywordAuthor | Antiferromagnetically coupled | - |
dc.subject.keywordAuthor | Immobilization | - |
dc.subject.keywordAuthor | Hexagonal mesoporous silica | - |
dc.subject.keywordAuthor | Heterogeneous catalysis | - |
dc.subject.keywordAuthor | Epoxidation | - |
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