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Concomitant polymorphism of an antiferromagnetically coupled dicopper(II,II) complex with single strand helical assembly: Synthesis, structure, DSC, magnetic and heterogeneous catalytic studies

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dc.contributor.authorMijanuddin, Md.-
dc.contributor.authorJana, Atish Dipankar-
dc.contributor.authorDrew, Michael G. B.-
dc.contributor.authorHong, Chang Seop-
dc.contributor.authorChattopadhyay, Basab-
dc.contributor.authorMukherjee, Monika-
dc.contributor.authorNandi, Mahasweta-
dc.contributor.authorBhaumik, Asim-
dc.contributor.authorHelliwell, Madeline-
dc.contributor.authorMostafa, Golam-
dc.contributor.authorAli, Mahammad-
dc.date.accessioned2021-09-08T18:54:06Z-
dc.date.available2021-09-08T18:54:06Z-
dc.date.created2021-06-10-
dc.date.issued2009-03-12-
dc.identifier.issn0277-5387-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/120429-
dc.description.abstractTwo concomitant polymorphic coordination complexes (dark blue - I and black - II) with the formula (Cu2C44H60N4O4) have been synthesized and characterized crystallographically. Magnetic measurements show the presence of a strong antiferromagnetic interaction and the 2J value corresponds extremely well to the theoretically calculated one, indicating the fact that it follows nicely the magneto-structural relationship. Immobilization of the copper(II) complex I on a 2D-hexagonal mesoporous silica showed good catalytic efficiency in the liquid phase partial oxidation of olefins in the presence of TBHP as an oxidant. (C) 2009 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectRAY CRYSTAL-STRUCTURES-
dc.subjectGALACTOSE-OXIDASE-
dc.subjectCOPPER(II) COMPLEXES-
dc.subjectAEROBIC OXIDATION-
dc.subjectCU-II-
dc.subjectDINUCLEAR COPPER(II)-
dc.subjectMOLECULAR-CRYSTALS-
dc.subjectMACROCYCLIC LIGAND-
dc.subjectMESOPOROUS SILICA-
dc.subjectPRIMARY ALCOHOLS-
dc.titleConcomitant polymorphism of an antiferromagnetically coupled dicopper(II,II) complex with single strand helical assembly: Synthesis, structure, DSC, magnetic and heterogeneous catalytic studies-
dc.typeArticle-
dc.contributor.affiliatedAuthorHong, Chang Seop-
dc.identifier.doi10.1016/j.poly.2008.12.047-
dc.identifier.scopusid2-s2.0-60349127695-
dc.identifier.wosid000264695400004-
dc.identifier.bibliographicCitationPOLYHEDRON, v.28, no.4, pp.665 - 672-
dc.relation.isPartOfPOLYHEDRON-
dc.citation.titlePOLYHEDRON-
dc.citation.volume28-
dc.citation.number4-
dc.citation.startPage665-
dc.citation.endPage672-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaCrystallography-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryCrystallography-
dc.subject.keywordPlusRAY CRYSTAL-STRUCTURES-
dc.subject.keywordPlusGALACTOSE-OXIDASE-
dc.subject.keywordPlusCOPPER(II) COMPLEXES-
dc.subject.keywordPlusAEROBIC OXIDATION-
dc.subject.keywordPlusCU-II-
dc.subject.keywordPlusDINUCLEAR COPPER(II)-
dc.subject.keywordPlusMOLECULAR-CRYSTALS-
dc.subject.keywordPlusMACROCYCLIC LIGAND-
dc.subject.keywordPlusMESOPOROUS SILICA-
dc.subject.keywordPlusPRIMARY ALCOHOLS-
dc.subject.keywordAuthorCu-II-complexes-
dc.subject.keywordAuthorConcomitant polymorphism-
dc.subject.keywordAuthorAntiferromagnetically coupled-
dc.subject.keywordAuthorImmobilization-
dc.subject.keywordAuthorHexagonal mesoporous silica-
dc.subject.keywordAuthorHeterogeneous catalysis-
dc.subject.keywordAuthorEpoxidation-
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