ScholarWorks@Korea University

Detailed Information

Cited 0 time in webofscience Cited 0 time in scopus
Metadata Downloads

An iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation

Full metadata record
DC Field Value Language
dc.contributor.authorAnnaraj, Jamespandi-
dc.contributor.authorKim, Soohee-
dc.contributor.authorSeo, Mi Sook-
dc.contributor.authorLee, Yong-Min-
dc.contributor.authorKim, Youngmee-
dc.contributor.authorKim, Sung-Jin-
dc.contributor.authorChoi, Young S.-
dc.contributor.authorJang, Ho G.-
dc.contributor.authorNam, Wonwoo-
dc.date.accessioned2021-09-08T19:37:49Z-
dc.date.available2021-09-08T19:37:49Z-
dc.date.created2021-06-18-
dc.date.issued2009-02-20-
dc.identifier.issn0020-1693-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/120569-
dc.description.abstractA new iron(II) complex bearing an N3S2 thioether ligand was synthesized and characterized with various spectroscopic techniques and X-ray crystallography. A mononuclear nonheme iron(IV)-oxo intermediate was generated in the reaction of the iron(II) complex with various terminal oxidants. Theiron (IV)-oxo species show a capability of epoxidizing olefins, and the olefin epoxidation occurs via an electrophilic oxidation mechanism. (C) 2008 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectNONHEME OXOIRON(IV) COMPLEXES-
dc.subjectSCHIFF-BASE LIGANDS-
dc.subjectDIOXYGEN ACTIVATION-
dc.subjectSPECTROSCOPIC CHARACTERIZATION-
dc.subjectOXO COMPLEXES-
dc.subjectMONONUCLEAR-
dc.subjectINTERMEDIATE-
dc.subjectOXYGENATION-
dc.subjectOXIDATION-
dc.subjectHEME-
dc.titleAn iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation-
dc.typeArticle-
dc.contributor.affiliatedAuthorJang, Ho G.-
dc.identifier.doi10.1016/j.ica.2008.04.018-
dc.identifier.scopusid2-s2.0-58849090591-
dc.identifier.wosid000262978000046-
dc.identifier.bibliographicCitationINORGANICA CHIMICA ACTA, v.362, no.3, pp.1031 - 1034-
dc.relation.isPartOfINORGANICA CHIMICA ACTA-
dc.citation.titleINORGANICA CHIMICA ACTA-
dc.citation.volume362-
dc.citation.number3-
dc.citation.startPage1031-
dc.citation.endPage1034-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.subject.keywordPlusNONHEME OXOIRON(IV) COMPLEXES-
dc.subject.keywordPlusSCHIFF-BASE LIGANDS-
dc.subject.keywordPlusDIOXYGEN ACTIVATION-
dc.subject.keywordPlusSPECTROSCOPIC CHARACTERIZATION-
dc.subject.keywordPlusOXO COMPLEXES-
dc.subject.keywordPlusMONONUCLEAR-
dc.subject.keywordPlusINTERMEDIATE-
dc.subject.keywordPlusOXYGENATION-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusHEME-
dc.subject.keywordAuthorOxygen activation-
dc.subject.keywordAuthorNonheme iron enzymes-
dc.subject.keywordAuthorBiomimetics-
dc.subject.keywordAuthorHigh-valent iron-oxo intermediate-
dc.subject.keywordAuthorEpoxidation-
Files in This Item
There are no files associated with this item.
Appears in
Collections
College of Science > Department of Chemistry > 1. Journal Articles
Show simple item record

qrcode

Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.

Altmetrics

Total Views & Downloads

STATISTICS
Total View :8,412,075
Today View :24,366

RSS_1.0 RSS_2.0 ATOM_1.0

CONTACT US

(02841) 서울특별시 성북구 안암로 14502-3290-1114

COPYRIGHT © 2021 Korea University. All Rights Reserved.

Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.

BROWSE

English