Photodegradation-induced Photoluminescence Behaviors of pi-Conjugated Polymers Upon the Doping of Organometallic Triplet Emitters
- Authors
- Chang, Jungyun; Yu, Young-Jun; Na, Jung Hoon; An, Jongdeok; Im, Chan; Choi, Dong-Hoon; Jin, Jung-Il; Lee, Seung Hee; Kim, Young Kwan
- Issue Date
- 15-11월-2008
- Publisher
- JOHN WILEY & SONS INC
- Keywords
- blending; conjugated polymer; degradation; light-emitting diodes (OLED); luminescence
- Citation
- JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, v.46, no.22, pp.2395 - 2403
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
- Volume
- 46
- Number
- 22
- Start Page
- 2395
- End Page
- 2403
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/122399
- DOI
- 10.1002/polb.21571
- ISSN
- 0887-6266
- Abstract
- The different effects on the photodegradation-induced photoluminescence (PL) of pi-conjugated polymeric thin films upon the doping of Ir(III) containing triplet emitters in ambient conditions at room temperature were investigated. In this study, we prepared spin-coated thin films using three different polymer matrices including poly(9-vinylcarbazole) (PVK), poly[9,9-bis(2-ethylhexyl)fluorene-2,7-diyl] (PF2/6), and poly[2-(5'-cyano-5'-methyl-hexyloxy)-1,4-phenylene] (CNPPP) derivatives doped with Ir(Ill) containing triplet emitters: Ir(III) bis[(4,6-fluorophenyl)-pyridinato-N,C2'] picolinate (FIrpic), or Ir(III)fac-tris(2-phenylpyridine) (Ir(ppy)(3)) or Ir(III)bis(2-(2'-benzothienyl) pyridinato-N-acetylacetonate) (Ir(btp)(2)acac). Using the doped films, and their neat films, on quartz substrates, the U-V-Visible absorption (UV-Vis) and PL spectra were recorded under continuous illumination with the excitation wavelengths at the absorption maxima of the corresponding matrix polymers. The dopant effects on the photodegradation-induced PL were extracted from the kinetic data obtained from the doped films by subtracting the mutual degradation kinetics of their corresponding neat films. The obtained dopant effects show a strong correlation between the photo-induced PL degradation and the exciton migration behaviors. (c) 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 2395-2403, 2008
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