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Asymmetric Desymmetrization of the Diallyl Acetals of Alkynals by the Enantioselective Pauson-Khand-Type Reaction Catalysts

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dc.contributor.authorKim, Dong Eun-
dc.contributor.authorLee, Bo Hyung-
dc.contributor.authorRajagopalasarma, Mudigonda-
dc.contributor.authorGenet, Jean-Pierre-
dc.contributor.authorRatovelomanana-Vidal, Virginie-
dc.contributor.authorJeong, Nakcheol-
dc.date.accessioned2021-09-09T02:51:40Z-
dc.date.available2021-09-09T02:51:40Z-
dc.date.created2021-06-10-
dc.date.issued2008-11-
dc.identifier.issn1615-4150-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/122432-
dc.description.abstractAsymmetric desymmetrization of the diallyl acetals of alkynal (1) by an enantioselective Pauson-Khand-type reaction catalyst was studied. The corresponding 5-oxabicyclo[3.3.0]octenones (2) were obtained as a mixture of diastereomers (2a and 2b), which were hydrolyzed to afford a single enantiomer (3), in high yields (up to 88%) as well as excellent enantioselectivities (up to 97%).-
dc.languageEnglish-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectCOMPLEX-
dc.titleAsymmetric Desymmetrization of the Diallyl Acetals of Alkynals by the Enantioselective Pauson-Khand-Type Reaction Catalysts-
dc.typeArticle-
dc.contributor.affiliatedAuthorJeong, Nakcheol-
dc.identifier.doi10.1002/adsc.200800514-
dc.identifier.scopusid2-s2.0-56749174861-
dc.identifier.wosid000261485400004-
dc.identifier.bibliographicCitationADVANCED SYNTHESIS & CATALYSIS, v.350, no.17, pp.2695 - 2700-
dc.relation.isPartOfADVANCED SYNTHESIS & CATALYSIS-
dc.citation.titleADVANCED SYNTHESIS & CATALYSIS-
dc.citation.volume350-
dc.citation.number17-
dc.citation.startPage2695-
dc.citation.endPage2700-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Applied-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusCOMPLEX-
dc.subject.keywordAuthorasymmetrric desymmetrization-
dc.subject.keywordAuthoratropisomeric ligands-
dc.subject.keywordAuthorenantioselective-
dc.subject.keywordAuthorPauson-Khand reaction-
dc.subject.keywordAuthorrhodium(I)-
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