Crown-6-calix[4]arene-capped calix[4]pyrrole: An ion-pair receptor for solvent-separated CsF ions
DC Field | Value | Language |
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dc.contributor.author | Sessler, Jonathan L. | - |
dc.contributor.author | Kim, Sung Kuk | - |
dc.contributor.author | Gross, Dustin E. | - |
dc.contributor.author | Lee, Chang-Hee | - |
dc.contributor.author | Kim, Jong Seung | - |
dc.contributor.author | Lynch, Vincent M. | - |
dc.date.accessioned | 2021-09-09T03:46:10Z | - |
dc.date.available | 2021-09-09T03:46:10Z | - |
dc.date.created | 2021-06-10 | - |
dc.date.issued | 2008-10-01 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/122581 | - |
dc.description.abstract | An ion-pair receptor, 1, containing both cation- and anion-recognizing sites, has been synthesized and characterized. Single-crystal X-ray diffraction structural studies and H-1 NMR spectroscopic analyses confirmed that 1 forms stable 1:1 complexes with CsF in solution and in the solid state in spite of the large separation enforced between the receptor-bound anion and cation. In 9:1 CDCl3/CD3OD, binding of fluoride anion within the calix[4]pyrrole core of 1 was not observed in the absence of a cobound cesium cation; however, it was seen in this solvent mixture under conditions where a Cs+ cation was bound to the crown ether-strapped calix[4]arene subunit. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | ANION-BINDING AGENTS | - |
dc.subject | MACROBICYCLIC RECEPTOR | - |
dc.subject | MOLECULAR RECOGNITION | - |
dc.subject | LIQUID-EXTRACTION | - |
dc.subject | COMPLEXATION | - |
dc.subject | CHEMISTRY | - |
dc.subject | TRANSPORT | - |
dc.subject | MEMBRANE | - |
dc.subject | CHANNELS | - |
dc.subject | ETHERS | - |
dc.title | Crown-6-calix[4]arene-capped calix[4]pyrrole: An ion-pair receptor for solvent-separated CsF ions | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Jong Seung | - |
dc.identifier.doi | 10.1021/ja804976f | - |
dc.identifier.scopusid | 2-s2.0-58149176013 | - |
dc.identifier.wosid | 000259553700063 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.130, no.39, pp.13162 - 13166 | - |
dc.relation.isPartOf | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 130 | - |
dc.citation.number | 39 | - |
dc.citation.startPage | 13162 | - |
dc.citation.endPage | 13166 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | ANION-BINDING AGENTS | - |
dc.subject.keywordPlus | MACROBICYCLIC RECEPTOR | - |
dc.subject.keywordPlus | MOLECULAR RECOGNITION | - |
dc.subject.keywordPlus | LIQUID-EXTRACTION | - |
dc.subject.keywordPlus | COMPLEXATION | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | MEMBRANE | - |
dc.subject.keywordPlus | CHANNELS | - |
dc.subject.keywordPlus | ETHERS | - |
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