Conformational study of jet-cooled L-phenylglycine
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hyung Min | - |
dc.contributor.author | Han, Kyu Young | - |
dc.contributor.author | Park, Juyeon | - |
dc.contributor.author | Kim, Seong Keun | - |
dc.contributor.author | Kim, Zee Hwan | - |
dc.date.accessioned | 2021-09-09T08:30:48Z | - |
dc.date.available | 2021-09-09T08:30:48Z | - |
dc.date.created | 2021-06-10 | - |
dc.date.issued | 2008-05-14 | - |
dc.identifier.issn | 0021-9606 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/123542 | - |
dc.description.abstract | We investigated the conformational structures of L-phenylglycine in the gas phase by photoionization and double resonance spectroscopy techniques as well as high-level ab initio calculations. The UV-UV and IR-UV double resonance spectroscopy suggested that there exists only one conformer that has a free OH band for the carboxyl group. Rotational contour analysis combined with ab initio calculation indicated that the conformer we detected by resonant two-photon ionization was not one of those found by Sanz in their microwave spectroscopic study [Chem. Eur. J. 12, 2564 (2006)]. Different methods of vaporization along with different expansion and cooling conditions and different detection methods are believed to be the culprit for such intriguing discrepancy. The identical hydrogen bonding structure of our phenylglycine conformer with the most abundant conformer of glycine found in helium droplets and their nearly identical OH frequencies suggest that the skeletal structure of glycine is not significantly altered by phenyl substitution. (C) 2008 American Institute of Physics. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER INST PHYSICS | - |
dc.subject | RESONANT 2-PHOTON IONIZATION | - |
dc.subject | POTENTIAL-ENERGY SURFACE | - |
dc.subject | L-PHENYLALANINE | - |
dc.subject | GLYCINE | - |
dc.subject | CONFORMERS | - |
dc.subject | CLUSTERS | - |
dc.subject | SPECTRUM | - |
dc.subject | SHAPE | - |
dc.title | Conformational study of jet-cooled L-phenylglycine | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Zee Hwan | - |
dc.identifier.doi | 10.1063/1.2918344 | - |
dc.identifier.scopusid | 2-s2.0-43949145259 | - |
dc.identifier.wosid | 000255983500033 | - |
dc.identifier.bibliographicCitation | JOURNAL OF CHEMICAL PHYSICS, v.128, no.18 | - |
dc.relation.isPartOf | JOURNAL OF CHEMICAL PHYSICS | - |
dc.citation.title | JOURNAL OF CHEMICAL PHYSICS | - |
dc.citation.volume | 128 | - |
dc.citation.number | 18 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Physics, Atomic, Molecular & Chemical | - |
dc.subject.keywordPlus | RESONANT 2-PHOTON IONIZATION | - |
dc.subject.keywordPlus | POTENTIAL-ENERGY SURFACE | - |
dc.subject.keywordPlus | L-PHENYLALANINE | - |
dc.subject.keywordPlus | GLYCINE | - |
dc.subject.keywordPlus | CONFORMERS | - |
dc.subject.keywordPlus | CLUSTERS | - |
dc.subject.keywordPlus | SPECTRUM | - |
dc.subject.keywordPlus | SHAPE | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.