Preparation of H5PMo10V2O40 catalyst immobilized on nitrogen-containing mesostructured cellular foam carbon (N-MCF-C) and its application to the vapor-phase oxidation of benzyl alcohol
DC Field | Value | Language |
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dc.contributor.author | Kim, Heesoo | - |
dc.contributor.author | Jung, Ji Chul | - |
dc.contributor.author | Park, Dong Ryul | - |
dc.contributor.author | Lee, Howon | - |
dc.contributor.author | Lee, Joohyung | - |
dc.contributor.author | Lee, Sang Hee | - |
dc.contributor.author | Baeck, Sung-Hyeon | - |
dc.contributor.author | Lee, Kwan-Young | - |
dc.contributor.author | Yi, Jongheop | - |
dc.contributor.author | Song, In Kyu | - |
dc.date.accessioned | 2021-09-09T09:54:40Z | - |
dc.date.available | 2021-09-09T09:54:40Z | - |
dc.date.created | 2021-06-10 | - |
dc.date.issued | 2008-03-31 | - |
dc.identifier.issn | 0920-5861 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/123865 | - |
dc.description.abstract | Nitrogen-containing mesostructured cellular foam carbon (N-MCF-C) was synthesized by a templating method using mesostructured cellular foam silica (MCF-S) and polypyrrole as a templating agent and a carbon precursor, respectively. The N-MCF-C was then modified to have a positive charge, and thus, to provide a site for the immobilization Of [PMo10V2O40](5-). By taking advantage of the overall negative charge of [PMo10V2O40](5-), H5PMo10V2O40 (PMo10V2) catalyst was chemically immobilized on the N-MCF-C support as a charge-matching component. Characterization results showed that the PMo10V2 catalyst was finely dispersed on the N-MCF-C support via strong chemical interaction, and that the pore structure of N-MCF-C was still maintained even after the immobilization of PMo10V2. In the vapor-phase oxidation of benzyl alcohol, the PMo10V2/N-MCF-C catalyst showed a higher conversion and a higher oxidation activity (formation of benzaldehyde) than the unsupported PMo10V2 and PMo10V2/MCF-S catalysts. (C) 2007 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.subject | SELECTIVE OXIDATION | - |
dc.subject | CONVERSION REACTION | - |
dc.subject | ACID | - |
dc.subject | SILICA | - |
dc.subject | SBA-15 | - |
dc.subject | OXYGEN | - |
dc.title | Preparation of H5PMo10V2O40 catalyst immobilized on nitrogen-containing mesostructured cellular foam carbon (N-MCF-C) and its application to the vapor-phase oxidation of benzyl alcohol | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Kwan-Young | - |
dc.identifier.doi | 10.1016/j.cattod.2007.12.004 | - |
dc.identifier.scopusid | 2-s2.0-43049151060 | - |
dc.identifier.wosid | 000254516800009 | - |
dc.identifier.bibliographicCitation | CATALYSIS TODAY, v.132, no.1-4, pp.58 - 62 | - |
dc.relation.isPartOf | CATALYSIS TODAY | - |
dc.citation.title | CATALYSIS TODAY | - |
dc.citation.volume | 132 | - |
dc.citation.number | 1-4 | - |
dc.citation.startPage | 58 | - |
dc.citation.endPage | 62 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Proceedings Paper | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | SELECTIVE OXIDATION | - |
dc.subject.keywordPlus | CONVERSION REACTION | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | SILICA | - |
dc.subject.keywordPlus | SBA-15 | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordAuthor | heteropolyacid | - |
dc.subject.keywordAuthor | nitrogen-containing mesostructured cellular foam carbon | - |
dc.subject.keywordAuthor | chemical immobilization | - |
dc.subject.keywordAuthor | benzyl alcohol oxidation | - |
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