X-ray scattering studies of phase-separated composite organic film cells

Abstract

The authors report X-ray scattering experiments on phase-separated composite organic film (PSCOF) structures mixed with ferroelectric liquid crystals (FLCs). We discuss the effect of the local layer structure in a PSCOF cell on the ratio of the concentration between prepolymer and liquid crystals. The ratio of optimized concentration in terms of optical characteristics for a PSCOF liquid crystal display are 30 wt % for prepolymer (NOA65) and 70 wt % for FLCs (Felix). We found that the layer structure in a ferroelectric liquid crystal cell made of 30 wt % NOA65 and 70 wt % Felix is a tilted-bookshelf layer structure. The angles 15 and 17 degrees are the tilted-bookshelf angles at 65 and 58 degrees C, respectively. These layer tilt angles are almost same as the molecular tilt angles of ferroelectric liquid crystals in the Sm C* phase. We understand that this result comes from compensating for layer buckling. We consider that the PSCOF-mode local layer structure is an excellent solution to the problem of zig-zag defects and mechanical shock for application in future televisions and plastic ferroelectric liquid crystal displays (FLCDs).