Measurement of high-pressure phase behavior for the benzyl (Meth)Acrylate in supercritical carbon dioxide from (313.2 to 393.2) K and pressures from (6 to 24) MPa
- Authors
- Liu, Shuang; Lim, Jong-Sung; Kang, Jung-Won; Byun, Hun-Soo
- Issue Date
- 1월-2008
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF CHEMICAL AND ENGINEERING DATA, v.53, no.1, pp.175 - 179
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF CHEMICAL AND ENGINEERING DATA
- Volume
- 53
- Number
- 1
- Start Page
- 175
- End Page
- 179
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/124506
- DOI
- 10.1021/je7004616
- ISSN
- 0021-9568
- Abstract
- High-pressure phase behavior is obtained for CO2 (1) + benzyl acrylate (2) and CO2 (1) + benzyl methacrylate (2) systems at (313.2, 333.2, 353.2, 373.2, and 393.2) K and pressures up to 24.43 MPa. The solubility of monomers for the CO2 (1) + benzyl acrylate (2) and CO2 (1) + benzyl methacrylate (2) systems increases as. the temperature increases at constant pressure. The CO2 (1) + benzyl acrylate (2) and CO2 (1) + benzyl methacrylate (2) systems exhibit type-I phase behavior. The experimental results for CO2 (1) + benzyl acrylate (2) and CO2 (1) + benzyl methacrylate (2) systems are correlated with the Peng-Robinson equation of state using a van der Waals one-fluid mixing rule including two adjustable parameters. Critical constants (P-c, T-c, and omega) are predicted with the Joback method and the Lee-Kesler method.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - Graduate School of Energy and Environment (KU-KIST GREEN SCHOOL) > Department of Energy and Environment > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.