Impregnation of tungstophosphoric acid on poly(methacrylamide-co-methyl methacrylate) and its acid catalytic activity in TMB alkylation
DC Field | Value | Language |
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dc.contributor.author | Lee, Dae-Won | - |
dc.contributor.author | Oh, Jung-Jun | - |
dc.contributor.author | Park, Young-Moo | - |
dc.contributor.author | Eom, Hee Jun | - |
dc.contributor.author | Yeom, Sung Ho | - |
dc.contributor.author | Song, In Kyu | - |
dc.contributor.author | Lee, Kwan-Young | - |
dc.date.accessioned | 2021-09-09T16:25:42Z | - |
dc.date.available | 2021-09-09T16:25:42Z | - |
dc.date.created | 2021-06-15 | - |
dc.date.issued | 2008 | - |
dc.identifier.issn | 0922-6168 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/125517 | - |
dc.description.abstract | A poly (methacrylamide-co-methylmethacrylate) (abbreviated PMAA-MMA) polymer support was studied for supporting a heteropolyacid (tungstophosphoric acid, H3PW12O40) with its surface positively charged in the polymerization step. PMAA-MMA supports could be obtained in a porous form by eliminating template reagent molecules (benzylmalonic acid) combined with properly selected monomer (methacrylamide). The amount of amine groups in PMAA-MMA directly determined the amount of H3PW12O40 impregnated, because the amine groups induced a positive charge on the PMAA-MMA surface. Finally, H3PW12O40/PMAA-MMA showed better acid catalytic activities than unsupported H3PW12O40 in alkylation of 1,3,5-trimethylbenzene with cyclohexene, which confirmed that PMAA-MMA supported H3PW12O40 effectively. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | SPRINGER | - |
dc.subject | IMMOBILIZATION | - |
dc.subject | ETHANOL | - |
dc.subject | SILICA | - |
dc.title | Impregnation of tungstophosphoric acid on poly(methacrylamide-co-methyl methacrylate) and its acid catalytic activity in TMB alkylation | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Dae-Won | - |
dc.contributor.affiliatedAuthor | Lee, Kwan-Young | - |
dc.identifier.doi | 10.1007/BF03036943 | - |
dc.identifier.scopusid | 2-s2.0-68349114858 | - |
dc.identifier.wosid | 000261578600022 | - |
dc.identifier.bibliographicCitation | RESEARCH ON CHEMICAL INTERMEDIATES, v.34, no.8-9, pp.817 - 825 | - |
dc.relation.isPartOf | RESEARCH ON CHEMICAL INTERMEDIATES | - |
dc.citation.title | RESEARCH ON CHEMICAL INTERMEDIATES | - |
dc.citation.volume | 34 | - |
dc.citation.number | 8-9 | - |
dc.citation.startPage | 817 | - |
dc.citation.endPage | 825 | - |
dc.type.rims | ART | - |
dc.type.docType | Article; Proceedings Paper | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | IMMOBILIZATION | - |
dc.subject.keywordPlus | ETHANOL | - |
dc.subject.keywordPlus | SILICA | - |
dc.subject.keywordAuthor | Heteropolyacid | - |
dc.subject.keywordAuthor | tungstophosphoric acid | - |
dc.subject.keywordAuthor | poly(methacrylamide-co-methylmethacrylate) | - |
dc.subject.keywordAuthor | 1,3,5-trimethylbenzene | - |
dc.subject.keywordAuthor | cyclohexene | - |
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