Amorphous hydrated vanadium oxide with enlarged interlayer spacing for aqueous zinc-ion batteries
DC Field | Value | Language |
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dc.contributor.author | Ju, Bobae | - |
dc.contributor.author | Song, Hee Jo | - |
dc.contributor.author | Yoon, Hyunseok | - |
dc.contributor.author | Kim, Dong-Wan | - |
dc.date.accessioned | 2021-11-16T11:40:53Z | - |
dc.date.available | 2021-11-16T11:40:53Z | - |
dc.date.created | 2021-08-30 | - |
dc.date.issued | 2021-09-15 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/127630 | - |
dc.description.abstract | Aqueous zinc-ion batteries (aqZIBs) are low cost and highly safe; however, the development of optimal cathode materials for them is challenging. Although layered vanadium oxides with high specific capacity have been extensively used as an aqZIB cathode material, the applicability of layered VO2.0.5H(2)O (VOH) as an aqZIB cathode material has not been investigated. In this light, herein, the electrochemical properties of a VOH cathode, prepared by a facile hydrothermal process, were examined and the applicability of the VOH cathode in aqZIBs was verified. VOH was electrochemically oxidized at high voltage during pre-charging; anodic oxidation caused a change in the valence state of VOH and induced an unexpected crystalline-to-amorphous phase transformation. Furthermore, the insertion of water in the pyramidal VO5 framework of oxidized VOH (ox-VOH) facilitated the highly reversible V3+/V5+ redox reaction with Zn ions. Moreover, ox-VOH was found to possess a highly stable amorphous phase and achieved high diffusion-controlled contribution at a low current density (50 mA g(-1)), affording superior, and stable long-term cyclability with similar to 88% retention after 240 cycles. These achievements signify a new milestone in developing suitable cathodes for high-performance aqZIBs. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | PERFORMANCE | - |
dc.subject | STORAGE | - |
dc.subject | CATHODE | - |
dc.subject | ENERGY | - |
dc.subject | WATER | - |
dc.subject | CO | - |
dc.title | Amorphous hydrated vanadium oxide with enlarged interlayer spacing for aqueous zinc-ion batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Dong-Wan | - |
dc.identifier.doi | 10.1016/j.cej.2021.130528 | - |
dc.identifier.scopusid | 2-s2.0-85108145251 | - |
dc.identifier.wosid | 000663707900005 | - |
dc.identifier.bibliographicCitation | CHEMICAL ENGINEERING JOURNAL, v.420 | - |
dc.relation.isPartOf | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.title | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.volume | 420 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | CATHODE | - |
dc.subject.keywordPlus | ENERGY | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | CO | - |
dc.subject.keywordAuthor | Anodic oxidation | - |
dc.subject.keywordAuthor | Amorphous phase | - |
dc.subject.keywordAuthor | Hydrated vanadium oxide | - |
dc.subject.keywordAuthor | Long-term cyclability | - |
dc.subject.keywordAuthor | Aqueous zinc-ion batteries | - |
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