Residual silica removal and nanopore generation on industrial waste silicon using ammonium fluoride and its application to lithium-ion battery anodes
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Wang, Sung Eun | - |
dc.contributor.author | Jang, Il-Seop | - |
dc.contributor.author | Kang, Yun Chan | - |
dc.contributor.author | Chun, Jinyoung | - |
dc.contributor.author | Jung, Dae-Soo | - |
dc.date.accessioned | 2021-11-16T13:40:16Z | - |
dc.date.available | 2021-11-16T13:40:16Z | - |
dc.date.created | 2021-08-30 | - |
dc.date.issued | 2021-09-01 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/127637 | - |
dc.description.abstract | Silicon is considered an important industrial element, primarily owing to its use in semiconductors, which are key components of various electronic devices; thus, the development of low-cost and efficient purification silicon processes has become a research focus. In this study, we developed a new process using ammonium fluoride (NH4F) to remove residual silica (SiO2) and generate nanopores on raw silicon (Si) materials without the use of highly toxic reagents and expensive procedures. We conducted low-temperature heat treatment of raw Si with NH4F under an inert atmosphere and found that the purity of raw Si was improved to a level similar to that of raw Si treated with hydrofluoric acid solution. Moreover, through this process, the surface area of raw Si was increased by surface tearing and the formation of nanopores. We also proposed a reaction mechanism for removing residual SiO2 from raw Si through X-ray diffraction analysis and demonstrated the safety of the process by analyzing the by-products generated during the heat treatment. When the modified Si material was applied to Li-ion battery anodes, they showed improved capacity, initial coulombic efficiency, and cycle performance as compared with those using raw Si material. We expect that this new NH4F-based method will not only be used to modify various Si materials for their efficient application, but will also be used to obtain nanostructured materials that require the removal of SiO2 during synthesis. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | IN-SITU | - |
dc.subject | NANOSTRUCTURED SILICON | - |
dc.subject | MESOPOROUS SILICON | - |
dc.subject | POROUS CARBON | - |
dc.subject | RICE HUSKS | - |
dc.subject | COMPOSITE | - |
dc.subject | ELECTRODES | - |
dc.subject | STORAGE | - |
dc.subject | PARTICLES | - |
dc.subject | GRAPHENE | - |
dc.title | Residual silica removal and nanopore generation on industrial waste silicon using ammonium fluoride and its application to lithium-ion battery anodes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kang, Yun Chan | - |
dc.identifier.doi | 10.1016/j.cej.2021.129389 | - |
dc.identifier.scopusid | 2-s2.0-85103669126 | - |
dc.identifier.wosid | 000663658700002 | - |
dc.identifier.bibliographicCitation | CHEMICAL ENGINEERING JOURNAL, v.419 | - |
dc.relation.isPartOf | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.title | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.volume | 419 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | IN-SITU | - |
dc.subject.keywordPlus | NANOSTRUCTURED SILICON | - |
dc.subject.keywordPlus | MESOPOROUS SILICON | - |
dc.subject.keywordPlus | POROUS CARBON | - |
dc.subject.keywordPlus | RICE HUSKS | - |
dc.subject.keywordPlus | COMPOSITE | - |
dc.subject.keywordPlus | ELECTRODES | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | PARTICLES | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordAuthor | Silica removal | - |
dc.subject.keywordAuthor | Porous silicon | - |
dc.subject.keywordAuthor | Ammonium fluoride | - |
dc.subject.keywordAuthor | Li-ion battery | - |
dc.subject.keywordAuthor | High capacity anode | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.