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New Types of o-Carborane-Based Chiral Phosphinooxazoline (Cab-PHOX) Ligand Systems: Synthesis and Characterization of Chiral Cab-PHOX Ligands and Their Application to Asymmetric Hydrogenation

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dc.contributor.authorLee, Jong-Dae-
dc.contributor.authorCo, Thanh Thien-
dc.contributor.authorKim, Tae-Jeong-
dc.contributor.authorKang, Sang Ook-
dc.date.accessioned2022-01-07T07:41:02Z-
dc.date.available2022-01-07T07:41:02Z-
dc.date.created2021-08-30-
dc.date.issued2009-03-17-
dc.identifier.issn0936-5214-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/134700-
dc.description.abstracto-Carborane-based chiral phosphinooxazoline (Cab-PHOX) ligands were synthesized for the first time and applied to the iridium and rhodium-catalyzed hydrogenation of unfunctionalized and functionalized olefins with an enantioselectivity of up to 98% and 96%, respectively. The modularity of the Cab-PHOX ligands is highlighted by the facile preparation of a variety of sterically and electronically different ligands.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherGEORG THIEME VERLAG KG-
dc.subjectCATALYZED ALLYLIC SUBSTITUTION-
dc.subjectENANTIOSELECTIVE HECK REACTIONS-
dc.subjectOXAZOLINE LIGANDS-
dc.subjectEFFICIENT SYNTHESIS-
dc.subjectPHOSPHORUS LIGANDS-
dc.subjectCRYSTAL-STRUCTURES-
dc.subjectMETAL-COMPLEXES-
dc.subjectP,N-LIGANDS-
dc.subjectOLEFINS-
dc.subjectALKENES-
dc.titleNew Types of o-Carborane-Based Chiral Phosphinooxazoline (Cab-PHOX) Ligand Systems: Synthesis and Characterization of Chiral Cab-PHOX Ligands and Their Application to Asymmetric Hydrogenation-
dc.typeArticle-
dc.contributor.affiliatedAuthorKang, Sang Ook-
dc.identifier.doi10.1055/s-0028-1087934-
dc.identifier.scopusid2-s2.0-62349091174-
dc.identifier.wosid000265025300017-
dc.identifier.bibliographicCitationSYNLETT, no.5, pp.771 - 774-
dc.relation.isPartOfSYNLETT-
dc.citation.titleSYNLETT-
dc.citation.number5-
dc.citation.startPage771-
dc.citation.endPage774-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.subject.keywordPlusCATALYZED ALLYLIC SUBSTITUTION-
dc.subject.keywordPlusENANTIOSELECTIVE HECK REACTIONS-
dc.subject.keywordPlusOXAZOLINE LIGANDS-
dc.subject.keywordPlusEFFICIENT SYNTHESIS-
dc.subject.keywordPlusPHOSPHORUS LIGANDS-
dc.subject.keywordPlusCRYSTAL-STRUCTURES-
dc.subject.keywordPlusMETAL-COMPLEXES-
dc.subject.keywordPlusP,N-LIGANDS-
dc.subject.keywordPlusOLEFINS-
dc.subject.keywordPlusALKENES-
dc.subject.keywordAuthorchiral phosphinooxazoline ligands-
dc.subject.keywordAuthoro-carborane-based bidentate ligands-
dc.subject.keywordAuthorasymmetric hydrogenation-
dc.subject.keywordAuthorunfunctionalized olefins-
dc.subject.keywordAuthorfunctionalized olefins-
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