Isomeric sp(2)-C-conjugated porous organic polymer-mediated photo- and sono-catalytic detoxification of sulfur mustard simulant under ambient conditions
DC Field | Value | Language |
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dc.contributor.author | Kim, Ji Hyeon | - |
dc.contributor.author | Yun, Hongryeol | - |
dc.contributor.author | Kang, Dong Won | - |
dc.contributor.author | Shin, Jinwoo | - |
dc.contributor.author | Kang, Minjung | - |
dc.contributor.author | Singh, Nem | - |
dc.contributor.author | Jeong, Ji-Eun | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.contributor.author | Kim, Jong Seung | - |
dc.date.accessioned | 2022-02-14T18:40:39Z | - |
dc.date.available | 2022-02-14T18:40:39Z | - |
dc.date.created | 2022-02-08 | - |
dc.date.issued | 2021-11-03 | - |
dc.identifier.issn | 2590-2393 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/135771 | - |
dc.description.abstract | The development of efficient strategies for the sustainable detoxification of mustard gas simulants has longstanding demand for human safety. Here, we present for the first time a photo- and sono-catalyzed selective detoxification of mustard gas simulants under ambient conditions using conveniently prepared porous organic polymer (POP) catalysts. We developed a microwave-assisted synthesis of three isomeric tetraphenylethylene-based POPs (TPo, TPm, and TPp) bearing fully sp(2)-hybridized carbon frameworks. Among the three isomers, TPm efficiently generated O-1(2), whereas TPp generated both O-2(center dot-) and HO center dot under visible light irradiation, both TPm and TPp efficiently generated ROS to selectively convert 2-chloroethyl ethyl sulfide (CEES) into nontoxic 2-chloroethyl ethyl sulfoxide (CEESO) in the atmospheric conditions, through a known conversion mechanism. TPm and TPp can also generate O-1(2) under ultrasound irradiation. This work provides insight into designing new POP photo- and sono-catalysts to generate ROS in widespread applications. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | SINGLET OXYGEN | - |
dc.subject | SELECTIVE PHOTOOXIDATION | - |
dc.subject | PHOTOCATALYTIC ACTIVITY | - |
dc.subject | GAS SIMULANT | - |
dc.subject | FRAMEWORKS | - |
dc.subject | OXIDATION | - |
dc.subject | FLUORESCENCE | - |
dc.subject | ULTRASOUND | - |
dc.subject | CHEMISTRY | - |
dc.subject | AIR | - |
dc.title | Isomeric sp(2)-C-conjugated porous organic polymer-mediated photo- and sono-catalytic detoxification of sulfur mustard simulant under ambient conditions | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.contributor.affiliatedAuthor | Kim, Jong Seung | - |
dc.identifier.doi | 10.1016/j.matt.2021.10.005 | - |
dc.identifier.scopusid | 2-s2.0-85123022301 | - |
dc.identifier.wosid | 000717526500008 | - |
dc.identifier.bibliographicCitation | MATTER, v.4, no.11, pp.3774 - 3785 | - |
dc.relation.isPartOf | MATTER | - |
dc.citation.title | MATTER | - |
dc.citation.volume | 4 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 3774 | - |
dc.citation.endPage | 3785 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | AIR | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | FLUORESCENCE | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | GAS SIMULANT | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | PHOTOCATALYTIC ACTIVITY | - |
dc.subject.keywordPlus | SELECTIVE PHOTOOXIDATION | - |
dc.subject.keywordPlus | SINGLET OXYGEN | - |
dc.subject.keywordPlus | ULTRASOUND | - |
dc.subject.keywordAuthor | MAP4: Demonstrate | - |
dc.subject.keywordAuthor | ambient condition | - |
dc.subject.keywordAuthor | chemical warfare agent | - |
dc.subject.keywordAuthor | photocatalyst | - |
dc.subject.keywordAuthor | porous organic polymer | - |
dc.subject.keywordAuthor | reactive oxygen species | - |
dc.subject.keywordAuthor | sonocatalyst | - |
dc.subject.keywordAuthor | sulfur mustard simulant | - |
dc.subject.keywordAuthor | sulfur oxidation | - |
dc.subject.keywordAuthor | ultrasound | - |
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