Mechanical Force for the Transformation of Aziridine into Imine
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Sangmin | - |
dc.contributor.author | Yoon, Hyo Jae | - |
dc.date.accessioned | 2022-02-16T18:42:18Z | - |
dc.date.available | 2022-02-16T18:42:18Z | - |
dc.date.created | 2022-02-08 | - |
dc.date.issued | 2021-10-25 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/136013 | - |
dc.description.abstract | Force-selective mechanochemical reactions may be important for applications in polymer mechanochemistry, yet it is difficult to achieve such reactions. This paper reports that cis-N-phthalimidoaziridine incorporated into a macromolecular backbone undergoes migration of N-phthalimido group to afford imine under mechanochemical condition and not thermal one. The imine is further hydrolyzed by water bifurcating into amine and aldehyde. These structural transformations are confirmed by H-1 NMR and FT-IR spectroscopic analyses. Computational simulations are conducted for the aziridine mechanophore to propose the mechanism of reaction and define the substrate scope of reaction. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | POLYMER | - |
dc.subject | MECHANOPHORE | - |
dc.subject | ACTIVATION | - |
dc.subject | CYCLOREVERSION | - |
dc.subject | REACTIVITY | - |
dc.subject | SCISSION | - |
dc.title | Mechanical Force for the Transformation of Aziridine into Imine | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yoon, Hyo Jae | - |
dc.identifier.doi | 10.1002/anie.202109358 | - |
dc.identifier.scopusid | 2-s2.0-85115849553 | - |
dc.identifier.wosid | 000700938400001 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.60, no.44, pp.23564 - 23568 | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 60 | - |
dc.citation.number | 44 | - |
dc.citation.startPage | 23564 | - |
dc.citation.endPage | 23568 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | CYCLOREVERSION | - |
dc.subject.keywordPlus | MECHANOPHORE | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | SCISSION | - |
dc.subject.keywordAuthor | aziridines | - |
dc.subject.keywordAuthor | mechanochemistry | - |
dc.subject.keywordAuthor | polymers | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordAuthor | structure elucidation | - |
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