Validating the Mott Formula with Self-Assembled Monolayer (SAM)-Based Large-Area Junctions: Effect of Length, Backbone, Spacer, Substituent, and Electrode on the Thermopower of SAMs
DC Field | Value | Language |
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dc.contributor.author | Park, Sohyun | - |
dc.contributor.author | Jang, Jiung | - |
dc.contributor.author | Yoon, Hyo Jae | - |
dc.date.accessioned | 2022-02-21T04:42:28Z | - |
dc.date.available | 2022-02-21T04:42:28Z | - |
dc.date.created | 2022-02-08 | - |
dc.date.issued | 2021-09-16 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/136341 | - |
dc.description.abstract | Understanding how the Seebeck effect of organic thermoelectric devices is associated with the chemical structure of active molecules within the devices is a key goal in organic and molecular thermoelectrics. This paper describes a series of physical-organic studies that investigate structure-thermopower relationships in self-assembled monolayers (SAMs) through measurements of the Seebeck coefficient (S, mu V/K) using the eutectic gallium-indium (EGaIn)-based junction technique. Several hypotheses were derived from a transmission function-based simple toy model, the Lorentzian transmission function-based Mott formula. These hypotheses were tested by comparing values of S for simple alkyl and aryl molecules with different structures F- in terms of backbone, length, spacer, anchor, and substituent, and for different electrodes (Au vs Ag), and by monitoring responses of S to the structural modifications. Experimentally obtained S values were further reconciled with values simulated by the Mott formula and with interfacial electronic structure and molecule-electrode coupling strength, independently measured by ultraviolet photoelectron spectroscopy and transition voltage spectroscopy. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | THERMAL-DESORPTION SPECTROSCOPY | - |
dc.subject | SINGLE-MOLECULE CONDUCTANCE | - |
dc.subject | THERMOELECTRIC PROPERTIES | - |
dc.subject | DEPENDENT THERMOPOWER | - |
dc.subject | CARBOXYLIC-ACIDS | - |
dc.subject | METAL-SURFACES | - |
dc.subject | GOLD | - |
dc.subject | SILVER | - |
dc.subject | BENZENEDITHIOL | - |
dc.subject | RECTIFICATION | - |
dc.title | Validating the Mott Formula with Self-Assembled Monolayer (SAM)-Based Large-Area Junctions: Effect of Length, Backbone, Spacer, Substituent, and Electrode on the Thermopower of SAMs | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yoon, Hyo Jae | - |
dc.identifier.doi | 10.1021/acs.jpcc.1c05623 | - |
dc.identifier.scopusid | 2-s2.0-85115621428 | - |
dc.identifier.wosid | 000697335100046 | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY C, v.125, no.36, pp.20035 - 20047 | - |
dc.relation.isPartOf | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.volume | 125 | - |
dc.citation.number | 36 | - |
dc.citation.startPage | 20035 | - |
dc.citation.endPage | 20047 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | BENZENEDITHIOL | - |
dc.subject.keywordPlus | CARBOXYLIC-ACIDS | - |
dc.subject.keywordPlus | DEPENDENT THERMOPOWER | - |
dc.subject.keywordPlus | GOLD | - |
dc.subject.keywordPlus | METAL-SURFACES | - |
dc.subject.keywordPlus | RECTIFICATION | - |
dc.subject.keywordPlus | SILVER | - |
dc.subject.keywordPlus | SINGLE-MOLECULE CONDUCTANCE | - |
dc.subject.keywordPlus | THERMAL-DESORPTION SPECTROSCOPY | - |
dc.subject.keywordPlus | THERMOELECTRIC PROPERTIES | - |
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