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Design of ultra-high luminescent polymers for organic photovoltaic cells with low energy loss

Authors
Wang, JingwenMa, LijiaoLee, Young WoongYao, HuifengXu, YeZhang, ShaoqingWoo, Han YoungHou, Jianhui
Issue Date
16-9월-2021
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.57, no.72, pp.9132 - 9135
Indexed
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
57
Number
72
Start Page
9132
End Page
9135
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/136345
DOI
10.1039/d1cc02706a
ISSN
1359-7345
Abstract
Here, new polymers named PBTT-Cn (n = 3, 4, or 5) have been designed based on carboxylate-functionalized thieno[3,2-b]thiophene units. The electroluminescence external quantum efficiencies (EQE(EL)) of pristine PBTT-C4 and C5 films are over 1 x 10(-2), which are among the highest results for OPV materials. Through combination with BTP-eC9, the PBTT-C4-based film showed a high EQE(EL) of 6 x 10(-4) and the Vnon-radloss is 0.19 eV. As a result, a high open-circuit voltage of 0.89 V and a satisfactory PCE of 15% were recorded in the PBTT-C4-based OPV cells.
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