Ultra-Deep-Blue Aggregation-Induced Delayed Fluorescence Emitters: Achieving Nearly 16% EQE in Solution-Processed Nondoped and Doped OLEDs with CIEy < 0.1
DC Field | Value | Language |
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dc.contributor.author | Kim, Hyung Jong | - |
dc.contributor.author | Kang, Hyunchul | - |
dc.contributor.author | Jeong, Ji-Eun | - |
dc.contributor.author | Park, Su Hong | - |
dc.contributor.author | Koh, Chang Woo | - |
dc.contributor.author | Kim, Chai Won | - |
dc.contributor.author | Woo, Han Young | - |
dc.contributor.author | Cho, Min Ju | - |
dc.contributor.author | Park, Sungnam | - |
dc.contributor.author | Choi, Dong Hoon | - |
dc.date.accessioned | 2022-02-26T02:40:51Z | - |
dc.date.available | 2022-02-26T02:40:51Z | - |
dc.date.created | 2022-02-09 | - |
dc.date.issued | 2021-08 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/136942 | - |
dc.description.abstract | Ultra-deep-blue aggregation-induced delayed fluorescence (AIDF) emitters (TB-tCz and TB-tPCz) bearing organoboron-based cores as acceptors and 3,6-substituted carbazoles as donors are presented. The thermally activated delayed fluorescence (TADF) properties of the two emitters are confirmed by theoretical calculations and time-resolved photoluminescence experiments. TB-tCz and TB-tPCz exhibit fast reverse intersystem crossing rate constants owing to efficient spin-orbit coupling between the singlet and triplet states. When applied in solution-processed organic light-emitting diodes (OLEDs), the TB-tCz- and TB-tPCz-based nondoped devices exhibit ultra-deep-blue emissions of 416-428 nm and high color purity owing to their narrow bandwidths of 42.2-44.4 nm, corresponding to the Commission International de l ' Eclairage color coordinates of (x = 0.16-0.17, y = 0.05-0.06). They show a maximum external quantum efficiency (EQE(max)) of 8.21% and 15.8%, respectively, exhibiting an unprecedented high performance in solution-processed deep-blue TADF-OLEDs. Furthermore, both emitters exhibit excellent device performances (EQE(max) = 14.1-15.9%) and color purity in solution-processed doped OLEDs. The current study provides an AIDF emitter design strategy to implement high-efficiency deep-blue OLEDs in the future. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | HIGH-EFFICIENCY | - |
dc.subject | PURE BLUE | - |
dc.subject | MOLECULAR DESIGN | - |
dc.subject | DONOR | - |
dc.subject | EMISSION | - |
dc.subject | POLYMERS | - |
dc.title | Ultra-Deep-Blue Aggregation-Induced Delayed Fluorescence Emitters: Achieving Nearly 16% EQE in Solution-Processed Nondoped and Doped OLEDs with CIEy < 0.1 | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.contributor.affiliatedAuthor | Park, Sungnam | - |
dc.identifier.doi | 10.1002/adfm.202102588 | - |
dc.identifier.scopusid | 2-s2.0-85107778402 | - |
dc.identifier.wosid | 000660400500001 | - |
dc.identifier.bibliographicCitation | ADVANCED FUNCTIONAL MATERIALS, v.31, no.33 | - |
dc.relation.isPartOf | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.title | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.volume | 31 | - |
dc.citation.number | 33 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | DONOR | - |
dc.subject.keywordPlus | EMISSION | - |
dc.subject.keywordPlus | HIGH-EFFICIENCY | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | MOLECULAR DESIGN | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | PURE BLUE | - |
dc.subject.keywordAuthor | aggregation-induced emission | - |
dc.subject.keywordAuthor | nondoped organic light emitting diodes | - |
dc.subject.keywordAuthor | solution processes | - |
dc.subject.keywordAuthor | thermally activated delayed fluorescence | - |
dc.subject.keywordAuthor | ultra-deep-blue emitters | - |
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